Synthesis and molecular structures of heterometallic complexes [RC5H4Fe(CO)2]2Sn(TePh)2 and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide

A. A. Pasynskii; Yu V. Torubaev; F. S. Denisov; A. N. Grechkin; K. A. Lyssenko; S. E. Nefedov; V. M. Novotortsev; Zh V. Dobrokhotova

doi:10.1007/BF02494823

Synthesis and molecular structures of heterometallic complexes [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide

A. A. Pasynskii, Yu V. Torubaev, F. S. Denisov, A. N. Grechkin, K. A. Lyssenko, S. E. Nefedov, V. M. Novotortsev, Zh V. Dobrokhotova

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Complexes [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ (R = H, Me) containing stable heterometallic Fe - Sn - Fe fragments with two phenyltellurium groups at the tin atom were synthesized from [RC₅H₄Fe(CO)₂]₂SnCl₂ (R = H, Me) and sodium phenyltelluride and their structures were established by X-ray analysis. Their chelates with tungsten tetracarbonyl, [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂[ W(CO)₄] (R = Me, H), and complexes with two Cr(CO)₅ fragments or dimeric trimethylplatinum iodide were synthesized and studied by X-ray analysis. Thermal decomposition of [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ complexes and their adducts with ML fragments (ML = W(CO)4, 2 Cr(CO)5, (Me3PtI)₂) into inorganic tellurides of a preset mixed-metal - chalcogenide composition was studied by differential scanning calorimetry. The temperature of complete elimination of organic fragments from methylcyclopentadienyl complexes is about 100 °C lower than in the case of cyclopentadienyl analogs.

Original language	English
Pages (from-to)	1744-1750
Number of pages	7
Journal	Russian Chemical Bulletin
Volume	48
Issue number	9
DOIs	https://doi.org/10.1007/BF02494823
State	Published - 1 Jan 1999
Externally published	Yes

Keywords

Chelates, metal - Metal bonds
Heterometallic complexes
Organotellurium ligands
Thermal decomposition
X-ray analysis

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF02494823

Cite this

Pasynskii, A. A., Torubaev, Y. V., Denisov, F. S., Grechkin, A. N., Lyssenko, K. A., Nefedov, S. E., Novotortsev, V. M., & Dobrokhotova, Z. V. (1999). Synthesis and molecular structures of heterometallic complexes [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide. Russian Chemical Bulletin, 48(9), 1744-1750. https://doi.org/10.1007/BF02494823

@article{a6d98b48b5cd45dd935df957d910282b,

title = "Synthesis and molecular structures of heterometallic complexes [RC5H4Fe(CO)2]2Sn(TePh)2 and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide",

abstract = "Complexes [RC5H4Fe(CO)2]2Sn(TePh)2 (R = H, Me) containing stable heterometallic Fe - Sn - Fe fragments with two phenyltellurium groups at the tin atom were synthesized from [RC5H4Fe(CO)2]2SnCl2 (R = H, Me) and sodium phenyltelluride and their structures were established by X-ray analysis. Their chelates with tungsten tetracarbonyl, [RC5H4Fe(CO)2]2Sn(TePh)2[ W(CO)4] (R = Me, H), and complexes with two Cr(CO)5 fragments or dimeric trimethylplatinum iodide were synthesized and studied by X-ray analysis. Thermal decomposition of [RC5H4Fe(CO)2]2Sn(TePh)2 complexes and their adducts with ML fragments (ML = W(CO)4, 2 Cr(CO)5, (Me3PtI)2) into inorganic tellurides of a preset mixed-metal - chalcogenide composition was studied by differential scanning calorimetry. The temperature of complete elimination of organic fragments from methylcyclopentadienyl complexes is about 100 °C lower than in the case of cyclopentadienyl analogs.",

keywords = "Chelates, metal - Metal bonds, Heterometallic complexes, Organotellurium ligands, Thermal decomposition, X-ray analysis",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Denisov, {F. S.} and Grechkin, {A. N.} and Lyssenko, {K. A.} and Nefedov, {S. E.} and Novotortsev, {V. M.} and Dobrokhotova, {Zh V.}",

note = "Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Project Nos. 97-03-33027 and 97-03-33172) and INTAS Foundation (Grant 96-1256).",

year = "1999",

month = jan,

day = "1",

doi = "10.1007/BF02494823",

language = "English",

volume = "48",

pages = "1744--1750",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

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Pasynskii, AA, Torubaev, YV, Denisov, FS, Grechkin, AN, Lyssenko, KA, Nefedov, SE, Novotortsev, VM & Dobrokhotova, ZV 1999, 'Synthesis and molecular structures of heterometallic complexes [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide', Russian Chemical Bulletin, vol. 48, no. 9, pp. 1744-1750. https://doi.org/10.1007/BF02494823

Synthesis and molecular structures of heterometallic complexes [RC₅H₄Fe(CO)₂]₂Sn(TePh)₂ and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide. / Pasynskii, A. A.; Torubaev, Yu V.; Denisov, F. S. et al.
In: Russian Chemical Bulletin, Vol. 48, No. 9, 01.01.1999, p. 1744-1750.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and molecular structures of heterometallic complexes [RC5H4Fe(CO)2]2Sn(TePh)2 and their adducts with chromium and tungsten carbonyls or with trimethylplatinum iodide

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Denisov, F. S.

AU - Grechkin, A. N.

AU - Lyssenko, K. A.

AU - Nefedov, S. E.

AU - Novotortsev, V. M.

AU - Dobrokhotova, Zh V.

N1 - Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Project Nos. 97-03-33027 and 97-03-33172) and INTAS Foundation (Grant 96-1256).

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Complexes [RC5H4Fe(CO)2]2Sn(TePh)2 (R = H, Me) containing stable heterometallic Fe - Sn - Fe fragments with two phenyltellurium groups at the tin atom were synthesized from [RC5H4Fe(CO)2]2SnCl2 (R = H, Me) and sodium phenyltelluride and their structures were established by X-ray analysis. Their chelates with tungsten tetracarbonyl, [RC5H4Fe(CO)2]2Sn(TePh)2[ W(CO)4] (R = Me, H), and complexes with two Cr(CO)5 fragments or dimeric trimethylplatinum iodide were synthesized and studied by X-ray analysis. Thermal decomposition of [RC5H4Fe(CO)2]2Sn(TePh)2 complexes and their adducts with ML fragments (ML = W(CO)4, 2 Cr(CO)5, (Me3PtI)2) into inorganic tellurides of a preset mixed-metal - chalcogenide composition was studied by differential scanning calorimetry. The temperature of complete elimination of organic fragments from methylcyclopentadienyl complexes is about 100 °C lower than in the case of cyclopentadienyl analogs.

AB - Complexes [RC5H4Fe(CO)2]2Sn(TePh)2 (R = H, Me) containing stable heterometallic Fe - Sn - Fe fragments with two phenyltellurium groups at the tin atom were synthesized from [RC5H4Fe(CO)2]2SnCl2 (R = H, Me) and sodium phenyltelluride and their structures were established by X-ray analysis. Their chelates with tungsten tetracarbonyl, [RC5H4Fe(CO)2]2Sn(TePh)2[ W(CO)4] (R = Me, H), and complexes with two Cr(CO)5 fragments or dimeric trimethylplatinum iodide were synthesized and studied by X-ray analysis. Thermal decomposition of [RC5H4Fe(CO)2]2Sn(TePh)2 complexes and their adducts with ML fragments (ML = W(CO)4, 2 Cr(CO)5, (Me3PtI)2) into inorganic tellurides of a preset mixed-metal - chalcogenide composition was studied by differential scanning calorimetry. The temperature of complete elimination of organic fragments from methylcyclopentadienyl complexes is about 100 °C lower than in the case of cyclopentadienyl analogs.

KW - Chelates, metal - Metal bonds

KW - Heterometallic complexes

KW - Organotellurium ligands

KW - Thermal decomposition

KW - X-ray analysis

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DO - 10.1007/BF02494823

M3 - Article

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