Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH2OH and CH2SCMe3

A. A. Pasynskii; Yu V. Torubaev; A. Yu Lyakina; R. I. Valiullina; G. G. Aleksandrov; K. A. Lysenko

Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH₂OH and CH₂SCMe₃

A. A. Pasynskii, Yu V. Torubaev, A. Yu Lyakina, R. I. Valiullina, G. G. Aleksandrov, K. A. Lysenko

Research output: Contribution to journal › Article › peer-review

Abstract

The replacement of one or two OH groups in [Co₂(CO)₆][μ-C₂(CH₂OH)₂] (I) by SCMe₃ in the presence of HBF₄ gave the corresponding π-complexes with thiolate-substituted acetylene, which were isolated as [(Ph₃P)Co₂(CO)₅][μ-C₂(CH₂SCMe₃)₂] (II) and [(Ph₃P)Co₂(CO)₅][μ-C₂(CH₂SCMe₃)(CH₂OH)] (III) single crystals after substituting PPh₃ for one CO group. The structures of II and III were determined by X-ray structural analysis. The geometry of the Co₂(CH₂C≡CCH₂) core was shown to weakly depend on the nature of substituents at the cobalt atoms, carbon atoms of the methylene groups, or sulfur atoms. It is suggested that the formal electron deficiency at the metal atoms π-coordinated by the triple C≡C bond has the decisive effect on the core geometry.

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	26
Issue number	2
State	Published - 1 Jan 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Cite this

@article{98997c8cc2824711a927b74a31d08c7c,

title = "Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH2OH and CH2SCMe3",

abstract = "The replacement of one or two OH groups in [Co2(CO)6][μ-C2(CH2OH)2] (I) by SCMe3 in the presence of HBF4 gave the corresponding π-complexes with thiolate-substituted acetylene, which were isolated as [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)2] (II) and [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)(CH2OH)] (III) single crystals after substituting PPh3 for one CO group. The structures of II and III were determined by X-ray structural analysis. The geometry of the Co2(CH2C≡CCH2) core was shown to weakly depend on the nature of substituents at the cobalt atoms, carbon atoms of the methylene groups, or sulfur atoms. It is suggested that the formal electron deficiency at the metal atoms π-coordinated by the triple C≡C bond has the decisive effect on the core geometry.",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Lyakina, {A. Yu} and Valiullina, {R. I.} and Aleksandrov, {G. G.} and Lysenko, {K. A.}",

year = "2000",

month = jan,

day = "1",

language = "English",

volume = "26",

pages = "107--111",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "2",

}

Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH₂OH and CH₂SCMe₃. / Pasynskii, A. A.; Torubaev, Yu V.; Lyakina, A. Yu et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 26, No. 2, 01.01.2000, p. 107-111.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH2OH and CH2SCMe3

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Lyakina, A. Yu

AU - Valiullina, R. I.

AU - Aleksandrov, G. G.

AU - Lysenko, K. A.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - The replacement of one or two OH groups in [Co2(CO)6][μ-C2(CH2OH)2] (I) by SCMe3 in the presence of HBF4 gave the corresponding π-complexes with thiolate-substituted acetylene, which were isolated as [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)2] (II) and [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)(CH2OH)] (III) single crystals after substituting PPh3 for one CO group. The structures of II and III were determined by X-ray structural analysis. The geometry of the Co2(CH2C≡CCH2) core was shown to weakly depend on the nature of substituents at the cobalt atoms, carbon atoms of the methylene groups, or sulfur atoms. It is suggested that the formal electron deficiency at the metal atoms π-coordinated by the triple C≡C bond has the decisive effect on the core geometry.

AB - The replacement of one or two OH groups in [Co2(CO)6][μ-C2(CH2OH)2] (I) by SCMe3 in the presence of HBF4 gave the corresponding π-complexes with thiolate-substituted acetylene, which were isolated as [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)2] (II) and [(Ph3P)Co2(CO)5][μ-C2(CH2SCMe3)(CH2OH)] (III) single crystals after substituting PPh3 for one CO group. The structures of II and III were determined by X-ray structural analysis. The geometry of the Co2(CH2C≡CCH2) core was shown to weakly depend on the nature of substituents at the cobalt atoms, carbon atoms of the methylene groups, or sulfur atoms. It is suggested that the formal electron deficiency at the metal atoms π-coordinated by the triple C≡C bond has the decisive effect on the core geometry.

UR - http://www.scopus.com/inward/record.url?scp=0033813649&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0033813649

SN - 1070-3284

VL - 26

SP - 107

EP - 111

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 2

ER -

Synthesis and molecular structures of the dicobalt carbonylphosphine π-complexes containing acetylene with functional groups CH₂OH and CH₂SCMe₃

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this