Synthesis and properties of (4-hydroxy-5-methoxycarbonylthieno)-tetrathiafulvalenes

I. V. Sudmale, V. Yu Khodorkovskii, A. S. Edzhinya, O. Ya Neiland

Research output: Contribution to journalArticlepeer-review

Abstract

6-Hydroxy-5-methoxycarbonylthieno[2,3-d]-1,3-dithiol-2-thione, -2-one, and 2-selenone were prepared by intramolecular cyclocondensation of 4-methoxycarbonylmethylthio-1,3-dithiol-2-thione-, 2-one-, and 2-selenone-5-carboxylic acid methyl ester. 2,6(7)-Di(methoxycarbonylmethylthio)-3,7(6)-di(methoxycarbonyl)tetra-thiafulvalene, 2-methoxycarbonylmethylthio-3-methoxycarbonyl-6,7-ethylenedithiotetrathiafulvalene, and the corresponding thieno-condensed tetrafulvalene derivatives were synthesized from them. The electrochemical oxidation potentials of the new tetrafulvalene derivatives were determined.

Original languageEnglish
Pages (from-to)652-658
Number of pages7
JournalChemistry of Heterocyclic Compounds
Volume29
Issue number6
DOIs
StatePublished - 1 Jun 1993

ASJC Scopus subject areas

  • Organic Chemistry

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