Synthesis and properties of some metalated carbonyl compounds

O. A. Kruglaya, I. B. Fedot'eva, B. V. Fedot'ev, I. D. Kalikhman, E. I. Brodskaya, N. S. Vyazankin

Research output: Contribution to journalArticlepeer-review

1 Scopus citations


1. Acetyl(triethylgermyl)carbene, which is formed by the decomposition of triethylgermyldiazoacetone over copper, is selectively inserted at the Ge-Hg bond of bis(triethylgermyl)mercury and the Ge-H bond of triethylgermane. 2. A new method was proposed for the synthesis of bis-metalated acetic acid esters, which is based on the reactions of carboalkoxy(triethylgermyl)carbenes with triethylsilane and its Ge and Sn analogs.

Original languageEnglish
Pages (from-to)1777-1779
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Issue number8
StatePublished - 1 Aug 1976
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry


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