Synthesis and properties of some metalated carbonyl compounds

O. A. Kruglaya; I. B. Fedot'eva; B. V. Fedot'ev; I. D. Kalikhman; E. I. Brodskaya; N. S. Vyazankin

doi:10.1007/BF00921458

Synthesis and properties of some metalated carbonyl compounds

O. A. Kruglaya
, I. B. Fedot'eva
, B. V. Fedot'ev
, I. D. Kalikhman
, E. I. Brodskaya
, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

1. Acetyl(triethylgermyl)carbene, which is formed by the decomposition of triethylgermyldiazoacetone over copper, is selectively inserted at the Ge-Hg bond of bis(triethylgermyl)mercury and the Ge-H bond of triethylgermane. 2. A new method was proposed for the synthesis of bis-metalated acetic acid esters, which is based on the reactions of carboalkoxy(triethylgermyl)carbenes with triethylsilane and its Ge and Sn analogs.

Original language	English
Pages (from-to)	1777-1779
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	25
Issue number	8
DOIs	https://doi.org/10.1007/BF00921458
State	Published - 1 Aug 1976
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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@article{77574aa4bdfa4807b198d51124e6845f,

title = "Synthesis and properties of some metalated carbonyl compounds",

abstract = "1. Acetyl(triethylgermyl)carbene, which is formed by the decomposition of triethylgermyldiazoacetone over copper, is selectively inserted at the Ge-Hg bond of bis(triethylgermyl)mercury and the Ge-H bond of triethylgermane. 2. A new method was proposed for the synthesis of bis-metalated acetic acid esters, which is based on the reactions of carboalkoxy(triethylgermyl)carbenes with triethylsilane and its Ge and Sn analogs.",

author = "Kruglaya, \{O. A.\} and Fedot'eva, \{I. B.\} and Fedot'ev, \{B. V.\} and Kalikhman, \{I. D.\} and Brodskaya, \{E. I.\} and Vyazankin, \{N. S.\}",

year = "1976",

month = aug,

day = "1",

doi = "10.1007/BF00921458",

language = "English",

volume = "25",

pages = "1777--1779",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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TY - JOUR

T1 - Synthesis and properties of some metalated carbonyl compounds

AU - Kruglaya, O. A.

AU - Fedot'eva, I. B.

AU - Fedot'ev, B. V.

AU - Kalikhman, I. D.

AU - Brodskaya, E. I.

AU - Vyazankin, N. S.

PY - 1976/8/1

Y1 - 1976/8/1

N2 - 1. Acetyl(triethylgermyl)carbene, which is formed by the decomposition of triethylgermyldiazoacetone over copper, is selectively inserted at the Ge-Hg bond of bis(triethylgermyl)mercury and the Ge-H bond of triethylgermane. 2. A new method was proposed for the synthesis of bis-metalated acetic acid esters, which is based on the reactions of carboalkoxy(triethylgermyl)carbenes with triethylsilane and its Ge and Sn analogs.

AB - 1. Acetyl(triethylgermyl)carbene, which is formed by the decomposition of triethylgermyldiazoacetone over copper, is selectively inserted at the Ge-Hg bond of bis(triethylgermyl)mercury and the Ge-H bond of triethylgermane. 2. A new method was proposed for the synthesis of bis-metalated acetic acid esters, which is based on the reactions of carboalkoxy(triethylgermyl)carbenes with triethylsilane and its Ge and Sn analogs.

UR - https://www.scopus.com/pages/publications/17144408847

U2 - 10.1007/BF00921458

DO - 10.1007/BF00921458

M3 - Article

AN - SCOPUS:17144408847

SN - 0568-5230

VL - 25

SP - 1777

EP - 1779

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 8

ER -

Synthesis and properties of some metalated carbonyl compounds

Abstract

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