Synthesis and reactions of organyl chloroethynyl sulfides with phosphorus-containing nucleophiles

A. N. Mirskova; S. G. Seredkina; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00953045

Synthesis and reactions of organyl chloroethynyl sulfides with phosphorus-containing nucleophiles

A. N. Mirskova, S. G. Seredkina, I. D. Kalikhman, M. G. Voronkov

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2 Scopus citations

Abstract

1. A method was proposed for the preparation of organyl chloroethynyl sulfides by the dehydrochlorination of organyl β, β-dichlorovinyl sulfide by alkali under phase-transfer catalysis conditions. 2. The reactions of organyl chloroethynyl sulfides with triphenylphosphine and triethyl phosphite lead to the products of the normal substitution of halogen in chloroacetylene, namely to organylthioethynylphosphonium chlorides and organylthioethynylphosphonates.

Original language	English
Pages (from-to)	2614-2617
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	34
Issue number	12
DOIs	https://doi.org/10.1007/BF00953045
State	Published - 1 Dec 1985
Externally published	Yes

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General Chemistry

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title = "Synthesis and reactions of organyl chloroethynyl sulfides with phosphorus-containing nucleophiles",

abstract = "1. A method was proposed for the preparation of organyl chloroethynyl sulfides by the dehydrochlorination of organyl β, β-dichlorovinyl sulfide by alkali under phase-transfer catalysis conditions. 2. The reactions of organyl chloroethynyl sulfides with triphenylphosphine and triethyl phosphite lead to the products of the normal substitution of halogen in chloroacetylene, namely to organylthioethynylphosphonium chlorides and organylthioethynylphosphonates.",

author = "Mirskova, {A. N.} and Seredkina, {S. G.} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1985",

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T1 - Synthesis and reactions of organyl chloroethynyl sulfides with phosphorus-containing nucleophiles

AU - Mirskova, A. N.

AU - Seredkina, S. G.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1985/12/1

Y1 - 1985/12/1

N2 - 1. A method was proposed for the preparation of organyl chloroethynyl sulfides by the dehydrochlorination of organyl β, β-dichlorovinyl sulfide by alkali under phase-transfer catalysis conditions. 2. The reactions of organyl chloroethynyl sulfides with triphenylphosphine and triethyl phosphite lead to the products of the normal substitution of halogen in chloroacetylene, namely to organylthioethynylphosphonium chlorides and organylthioethynylphosphonates.

AB - 1. A method was proposed for the preparation of organyl chloroethynyl sulfides by the dehydrochlorination of organyl β, β-dichlorovinyl sulfide by alkali under phase-transfer catalysis conditions. 2. The reactions of organyl chloroethynyl sulfides with triphenylphosphine and triethyl phosphite lead to the products of the normal substitution of halogen in chloroacetylene, namely to organylthioethynylphosphonium chlorides and organylthioethynylphosphonates.

UR - http://www.scopus.com/inward/record.url?scp=0001838986&partnerID=8YFLogxK

U2 - 10.1007/BF00953045

DO - 10.1007/BF00953045

M3 - Article

AN - SCOPUS:0001838986

SN - 0568-5230

VL - 34

SP - 2614

EP - 2617

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 12

ER -

Synthesis and reactions of organyl chloroethynyl sulfides with phosphorus-containing nucleophiles

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