Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)2SC(O)Ph, [CpMn(CO)2] 2(μ-Se2), CpMn(CO)2SMe2, [CpMn(CO)2]2(μ-SMe2), and [CpMn(CO) 2]2(μ-SeMe2)

A. A. Pasynskii; V. N. Grigor'ev; Yu V. Torubaev; K. A. Lysenko; Zh V. Dobrokhotova; V. V. Minin; V. A. Grinberg

Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)₂SC(O)Ph, [CpMn(CO)₂] ₂(μ-Se₂), CpMn(CO)₂SMe₂, [CpMn(CO)₂]₂(μ-SMe₂), and [CpMn(CO) ₂]₂(μ-SeMe₂)

A. A. Pasynskii
, V. N. Grigor'ev
, Yu V. Torubaev
, K. A. Lysenko
, Zh V. Dobrokhotova
, V. V. Minin
, V. A. Grinberg

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The reaction of [CpMn(CO)₂C(O)Ph]^-Li⁺ with an equimolar amount of sulfur gives the paramagnetic thiocarboxylate complex CpMn(CO)₂SC(O)Ph (1), which is converted on treatment with sulfur into the known binuclear diamagnetic complex [CpMn(CO)₂] ₂(μ-S₂) (2). Treatment of [CpMn(CO)₂C(O)Ph] ^-Li⁺ with elemental selenium under similar conditions gives the dimer [CpMn(CO)₂]₂(μ-Se₂) (3). The reduction of 2 and 3 by sodium borohydride followed by the reaction with methyl iodide affords the mononuclear complex CpMn(CO)₂SMe₂ (4) and binuclear complexes [CpMn(CO)₂]₂(μ-XMe₂) (X = S (5), Se (6)). On heating in hexane, 4 is converted into 5. The structures of complexes 1 and 3-6 were characterized by X-ray diffraction. The EPR spectrum of 1, the electrochemical behavior of 2 and 3, and the thermal decomposition of 2, 3, 5, and 6 were investigated.

Original language	English
Pages (from-to)	1833-1841
Number of pages	9
Journal	Russian Journal of Inorganic Chemistry
Volume	47
Issue number	12
State	Published - 1 Jan 2002
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

Pasynskii, A. A., Grigor'ev, V. N., Torubaev, Y. V., Lysenko, K. A., Dobrokhotova, Z. V., Minin, V. V., & Grinberg, V. A. (2002). Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)₂SC(O)Ph, [CpMn(CO)₂] ₂(μ-Se₂), CpMn(CO)₂SMe₂, [CpMn(CO)₂]₂(μ-SMe₂), and [CpMn(CO) ₂]₂(μ-SeMe₂). Russian Journal of Inorganic Chemistry, 47(12), 1833-1841.

@article{efe9bcdc46b84fb1be74109dec1e64d1,

title = "Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)2SC(O)Ph, [CpMn(CO)2] 2(μ-Se2), CpMn(CO)2SMe2, [CpMn(CO)2]2(μ-SMe2), and [CpMn(CO) 2]2(μ-SeMe2)",

abstract = "The reaction of [CpMn(CO)2C(O)Ph]-Li+ with an equimolar amount of sulfur gives the paramagnetic thiocarboxylate complex CpMn(CO)2SC(O)Ph (1), which is converted on treatment with sulfur into the known binuclear diamagnetic complex [CpMn(CO)2] 2(μ-S2) (2). Treatment of [CpMn(CO)2C(O)Ph] -Li+ with elemental selenium under similar conditions gives the dimer [CpMn(CO)2]2(μ-Se2) (3). The reduction of 2 and 3 by sodium borohydride followed by the reaction with methyl iodide affords the mononuclear complex CpMn(CO)2SMe2 (4) and binuclear complexes [CpMn(CO)2]2(μ-XMe2) (X = S (5), Se (6)). On heating in hexane, 4 is converted into 5. The structures of complexes 1 and 3-6 were characterized by X-ray diffraction. The EPR spectrum of 1, the electrochemical behavior of 2 and 3, and the thermal decomposition of 2, 3, 5, and 6 were investigated.",

author = "Pasynskii, \{A. A.\} and Grigor'ev, \{V. N.\} and Torubaev, \{Yu V.\} and Lysenko, \{K. A.\} and Dobrokhotova, \{Zh V.\} and Minin, \{V. V.\} and Grinberg, \{V. A.\}",

year = "2002",

month = jan,

day = "1",

language = "English",

volume = "47",

pages = "1833--1841",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "12",

}

Pasynskii, AA, Grigor'ev, VN, Torubaev, YV, Lysenko, KA, Dobrokhotova, ZV, Minin, VV & Grinberg, VA 2002, 'Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)₂SC(O)Ph, [CpMn(CO)₂] ₂(μ-Se₂), CpMn(CO)₂SMe₂, [CpMn(CO)₂]₂(μ-SMe₂), and [CpMn(CO) ₂]₂(μ-SeMe₂)', Russian Journal of Inorganic Chemistry, vol. 47, no. 12, pp. 1833-1841.

Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)₂SC(O)Ph, [CpMn(CO)₂] ₂(μ-Se₂), CpMn(CO)₂SMe₂, [CpMn(CO)₂]₂(μ-SMe₂), and [CpMn(CO) ₂]₂(μ-SeMe₂). / Pasynskii, A. A.; Grigor'ev, V. N.; Torubaev, Yu V. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 47, No. 12, 01.01.2002, p. 1833-1841.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)2SC(O)Ph, [CpMn(CO)2] 2(μ-Se2), CpMn(CO)2SMe2, [CpMn(CO)2]2(μ-SMe2), and [CpMn(CO) 2]2(μ-SeMe2)

AU - Pasynskii, A. A.

AU - Grigor'ev, V. N.

AU - Torubaev, Yu V.

AU - Lysenko, K. A.

AU - Dobrokhotova, Zh V.

AU - Minin, V. V.

AU - Grinberg, V. A.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The reaction of [CpMn(CO)2C(O)Ph]-Li+ with an equimolar amount of sulfur gives the paramagnetic thiocarboxylate complex CpMn(CO)2SC(O)Ph (1), which is converted on treatment with sulfur into the known binuclear diamagnetic complex [CpMn(CO)2] 2(μ-S2) (2). Treatment of [CpMn(CO)2C(O)Ph] -Li+ with elemental selenium under similar conditions gives the dimer [CpMn(CO)2]2(μ-Se2) (3). The reduction of 2 and 3 by sodium borohydride followed by the reaction with methyl iodide affords the mononuclear complex CpMn(CO)2SMe2 (4) and binuclear complexes [CpMn(CO)2]2(μ-XMe2) (X = S (5), Se (6)). On heating in hexane, 4 is converted into 5. The structures of complexes 1 and 3-6 were characterized by X-ray diffraction. The EPR spectrum of 1, the electrochemical behavior of 2 and 3, and the thermal decomposition of 2, 3, 5, and 6 were investigated.

AB - The reaction of [CpMn(CO)2C(O)Ph]-Li+ with an equimolar amount of sulfur gives the paramagnetic thiocarboxylate complex CpMn(CO)2SC(O)Ph (1), which is converted on treatment with sulfur into the known binuclear diamagnetic complex [CpMn(CO)2] 2(μ-S2) (2). Treatment of [CpMn(CO)2C(O)Ph] -Li+ with elemental selenium under similar conditions gives the dimer [CpMn(CO)2]2(μ-Se2) (3). The reduction of 2 and 3 by sodium borohydride followed by the reaction with methyl iodide affords the mononuclear complex CpMn(CO)2SMe2 (4) and binuclear complexes [CpMn(CO)2]2(μ-XMe2) (X = S (5), Se (6)). On heating in hexane, 4 is converted into 5. The structures of complexes 1 and 3-6 were characterized by X-ray diffraction. The EPR spectrum of 1, the electrochemical behavior of 2 and 3, and the thermal decomposition of 2, 3, 5, and 6 were investigated.

UR - https://www.scopus.com/pages/publications/8744227992

M3 - Article

AN - SCOPUS:8744227992

SN - 0036-0236

VL - 47

SP - 1833

EP - 1841

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 12

ER -

Synthesis, molecular structures, and properties of the manganese chalcogenide complexes CpMn(CO)₂SC(O)Ph, [CpMn(CO)₂] ₂(μ-Se₂), CpMn(CO)₂SMe₂, [CpMn(CO)₂]₂(μ-SMe₂), and [CpMn(CO) ₂]₂(μ-SeMe₂)

Abstract

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