Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2

Yury V. Torubaev; Alexander A. Pasynskii; Alina V. Pavlova; Mohd Tauqeer; Rolfe H. Herber; Israel Nowik; Ivan V. Skabitskii; Gleb L. Denisov; Vitaly A. Grinberg; Pradeep Mathur; Mobin M. Shaikh; Goutam K. Lahiri

doi:10.1016/j.jorganchem.2014.11.025

Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂

Yury V. Torubaev, Alexander A. Pasynskii, Alina V. Pavlova, Mohd Tauqeer, Rolfe H. Herber, Israel Nowik, Ivan V. Skabitskii, Gleb L. Denisov, Vitaly A. Grinberg, Pradeep Mathur, Mobin M. Shaikh, Goutam K. Lahiri

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)₅ gave complex (Fc₂Te₂)Fe(CO)₃I₂ (1) bearing an Fc₂Te₂ ligand, or a dimeric complex [(CO)₃IFe(μ-TeFc)]₂ (2). An interaction of equimolar amounts of [CpFe(CO)₂]₂ and Fc₂Te₂ under the thermal conditions in toluene afforded CpFe(CO)₂TeFc (3). Complex 3 can be easily halogenated at the Te center by elemental bromine and iodine to give monomeric CpFe(CO)₂TeX₂Fc (X = Br (4), I (5)). Complex 5 can be prepared alternatively via formal insertion of [FcTeI] into Fc-I bond of CpFe(CO)₂I. Complex 3 readily substitutes one carbonyl in Fe(CO)₄I₂ to give the adduct CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂ (6).

Original language	English
Pages (from-to)	88-95
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	777
DOIs	https://doi.org/10.1016/j.jorganchem.2014.11.025
State	Published - 1 Feb 2015
Externally published	Yes

Keywords

Electrochemistry
Ferrocenyl
Metal-chalcogenide
Mössbauer spectroscopy
Organotellurium
X-ray diffraction

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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Torubaev, Y. V., Pasynskii, A. A., Pavlova, A. V., Tauqeer, M., Herber, R. H., Nowik, I., Skabitskii, I. V., Denisov, G. L., Grinberg, V. A., Mathur, P., Shaikh, M. M., & Lahiri, G. K. (2015). Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂. Journal of Organometallic Chemistry, 777, 88-95. https://doi.org/10.1016/j.jorganchem.2014.11.025

Torubaev, Yury V. ; Pasynskii, Alexander A. ; Pavlova, Alina V. et al. / Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives : (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂. In: Journal of Organometallic Chemistry. 2015 ; Vol. 777. pp. 88-95.

@article{f2dfea8f7b7f40db9701064494997372,

title = "Synthesis, molecular structures, M{\"o}ssbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2",

abstract = "Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)5 gave complex (Fc2Te2)Fe(CO)3I2 (1) bearing an Fc2Te2 ligand, or a dimeric complex [(CO)3IFe(μ-TeFc)]2 (2). An interaction of equimolar amounts of [CpFe(CO)2]2 and Fc2Te2 under the thermal conditions in toluene afforded CpFe(CO)2TeFc (3). Complex 3 can be easily halogenated at the Te center by elemental bromine and iodine to give monomeric CpFe(CO)2TeX2Fc (X = Br (4), I (5)). Complex 5 can be prepared alternatively via formal insertion of [FcTeI] into Fc-I bond of CpFe(CO)2I. Complex 3 readily substitutes one carbonyl in Fe(CO)4I2 to give the adduct CpFe(CO)2(μ-TeFc)Fe(CO)3I2 (6).",

keywords = "Electrochemistry, Ferrocenyl, Metal-chalcogenide, M{\"o}ssbauer spectroscopy, Organotellurium, X-ray diffraction",

author = "Torubaev, \{Yury V.\} and Pasynskii, \{Alexander A.\} and Pavlova, \{Alina V.\} and Mohd Tauqeer and Herber, \{Rolfe H.\} and Israel Nowik and Skabitskii, \{Ivan V.\} and Denisov, \{Gleb L.\} and Grinberg, \{Vitaly A.\} and Pradeep Mathur and Shaikh, \{Mobin M.\} and Lahiri, \{Goutam K.\}",

note = "Publisher Copyright: {\textcopyright} 2014 Elsevier B.V.",

year = "2015",

month = feb,

day = "1",

doi = "10.1016/j.jorganchem.2014.11.025",

language = "English",

volume = "777",

pages = "88--95",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

Torubaev, YV, Pasynskii, AA, Pavlova, AV, Tauqeer, M, Herber, RH, Nowik, I, Skabitskii, IV, Denisov, GL, Grinberg, VA, Mathur, P, Shaikh, MM & Lahiri, GK 2015, 'Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂', Journal of Organometallic Chemistry, vol. 777, pp. 88-95. https://doi.org/10.1016/j.jorganchem.2014.11.025

Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂. / Torubaev, Yury V.; Pasynskii, Alexander A.; Pavlova, Alina V. et al.
In: Journal of Organometallic Chemistry, Vol. 777, 01.02.2015, p. 88-95.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives

T2 - (Fc2Te2)Fe(CO)3I2 [(CO)3IFe(μ-TeFc)]2, CpFe(CO)2TeFc, CpFe(CO)2TeX2Fc (X = Br, I) and CpFe(CO)2(μ-TeFc)Fe(CO)3I2

AU - Torubaev, Yury V.

AU - Pasynskii, Alexander A.

AU - Pavlova, Alina V.

AU - Tauqeer, Mohd

AU - Herber, Rolfe H.

AU - Nowik, Israel

AU - Skabitskii, Ivan V.

AU - Denisov, Gleb L.

AU - Grinberg, Vitaly A.

AU - Mathur, Pradeep

AU - Shaikh, Mobin M.

AU - Lahiri, Goutam K.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)5 gave complex (Fc2Te2)Fe(CO)3I2 (1) bearing an Fc2Te2 ligand, or a dimeric complex [(CO)3IFe(μ-TeFc)]2 (2). An interaction of equimolar amounts of [CpFe(CO)2]2 and Fc2Te2 under the thermal conditions in toluene afforded CpFe(CO)2TeFc (3). Complex 3 can be easily halogenated at the Te center by elemental bromine and iodine to give monomeric CpFe(CO)2TeX2Fc (X = Br (4), I (5)). Complex 5 can be prepared alternatively via formal insertion of [FcTeI] into Fc-I bond of CpFe(CO)2I. Complex 3 readily substitutes one carbonyl in Fe(CO)4I2 to give the adduct CpFe(CO)2(μ-TeFc)Fe(CO)3I2 (6).

AB - Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)5 gave complex (Fc2Te2)Fe(CO)3I2 (1) bearing an Fc2Te2 ligand, or a dimeric complex [(CO)3IFe(μ-TeFc)]2 (2). An interaction of equimolar amounts of [CpFe(CO)2]2 and Fc2Te2 under the thermal conditions in toluene afforded CpFe(CO)2TeFc (3). Complex 3 can be easily halogenated at the Te center by elemental bromine and iodine to give monomeric CpFe(CO)2TeX2Fc (X = Br (4), I (5)). Complex 5 can be prepared alternatively via formal insertion of [FcTeI] into Fc-I bond of CpFe(CO)2I. Complex 3 readily substitutes one carbonyl in Fe(CO)4I2 to give the adduct CpFe(CO)2(μ-TeFc)Fe(CO)3I2 (6).

KW - Electrochemistry

KW - Ferrocenyl

KW - Metal-chalcogenide

KW - Mössbauer spectroscopy

KW - Organotellurium

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84919725967

U2 - 10.1016/j.jorganchem.2014.11.025

DO - 10.1016/j.jorganchem.2014.11.025

M3 - Article

AN - SCOPUS:84919725967

SN - 0022-328X

VL - 777

SP - 88

EP - 95

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Torubaev YV, Pasynskii AA, Pavlova AV, Tauqeer M, Herber RH, Nowik I et al. Synthesis, molecular structures, Mössbauer and electrochemical investigation of ferrocenyltelluride derivatives: (Fc₂Te₂)Fe(CO)₃I₂ [(CO)₃IFe(μ-TeFc)]₂, CpFe(CO)₂TeFc, CpFe(CO)₂TeX₂Fc (X = Br, I) and CpFe(CO)₂(μ-TeFc)Fe(CO)₃I₂. Journal of Organometallic Chemistry. 2015 Feb 1;777:88-95. doi: 10.1016/j.jorganchem.2014.11.025