Synthesis of 2-acylmethyl- and 2-acylmethylenebenzo-1,3-dithioles from α-alkynyl ketones

V. N. Elokhina; A. S. Nakhmanovich; R. V. Karnaukhova; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00505984

Synthesis of 2-acylmethyl- and 2-acylmethylenebenzo-1,3-dithioles from α-alkynyl ketones

V. N. Elokhina
, A. S. Nakhmanovich
, R. V. Karnaukhova
, I. D. Kalikhman
, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of α-alkynyl ketones with o-phenylenedithiol, which leads to the formation of 2-acylmethylbenzo-1,3-dithioles, was investigated. Reactions of the latter with hydrazine hydrate and hydroxylamine and oxidation were realized. Difficult-to-obtain 2-acylmethylenebenzo-1,3-dithioles were obtained by the reaction of α-bromoalkynyl ketones with o-phenylenedithiol. The IR and PMR spectra of the synthesized compounds are presented.

Original language	English
Pages (from-to)	235-239
Number of pages	5
Journal	Chemistry of Heterocyclic Compounds
Volume	17
Issue number	3
DOIs	https://doi.org/10.1007/BF00505984
State	Published - 1 Mar 1981
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Synthesis of 2-acylmethyl- and 2-acylmethylenebenzo-1,3-dithioles from α-alkynyl ketones",

abstract = "The reaction of α-alkynyl ketones with o-phenylenedithiol, which leads to the formation of 2-acylmethylbenzo-1,3-dithioles, was investigated. Reactions of the latter with hydrazine hydrate and hydroxylamine and oxidation were realized. Difficult-to-obtain 2-acylmethylenebenzo-1,3-dithioles were obtained by the reaction of α-bromoalkynyl ketones with o-phenylenedithiol. The IR and PMR spectra of the synthesized compounds are presented.",

author = "Elokhina, \{V. N.\} and Nakhmanovich, \{A. S.\} and Karnaukhova, \{R. V.\} and Kalikhman, \{I. D.\} and Voronkov, \{M. G.\}",

year = "1981",

month = mar,

day = "1",

doi = "10.1007/BF00505984",

language = "English",

volume = "17",

pages = "235--239",

journal = "Chemistry of Heterocyclic Compounds",

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T1 - Synthesis of 2-acylmethyl- and 2-acylmethylenebenzo-1,3-dithioles from α-alkynyl ketones

AU - Elokhina, V. N.

AU - Nakhmanovich, A. S.

AU - Karnaukhova, R. V.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1981/3/1

Y1 - 1981/3/1

N2 - The reaction of α-alkynyl ketones with o-phenylenedithiol, which leads to the formation of 2-acylmethylbenzo-1,3-dithioles, was investigated. Reactions of the latter with hydrazine hydrate and hydroxylamine and oxidation were realized. Difficult-to-obtain 2-acylmethylenebenzo-1,3-dithioles were obtained by the reaction of α-bromoalkynyl ketones with o-phenylenedithiol. The IR and PMR spectra of the synthesized compounds are presented.

AB - The reaction of α-alkynyl ketones with o-phenylenedithiol, which leads to the formation of 2-acylmethylbenzo-1,3-dithioles, was investigated. Reactions of the latter with hydrazine hydrate and hydroxylamine and oxidation were realized. Difficult-to-obtain 2-acylmethylenebenzo-1,3-dithioles were obtained by the reaction of α-bromoalkynyl ketones with o-phenylenedithiol. The IR and PMR spectra of the synthesized compounds are presented.

UR - https://www.scopus.com/pages/publications/34250240486

U2 - 10.1007/BF00505984

DO - 10.1007/BF00505984

M3 - Article

AN - SCOPUS:34250240486

SN - 0009-3122

VL - 17

SP - 235

EP - 239

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 3

ER -

Synthesis of 2-acylmethyl- and 2-acylmethylenebenzo-1,3-dithioles from α-alkynyl ketones

Abstract

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