Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry

Ying Li; Taiho Park; J. Kwansima Quansah; Steven C. Zimmerman

doi:10.1021/ja2069278

Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry

Ying Li, Taiho Park, J. Kwansima Quansah, Steven C. Zimmerman

Research output: Contribution to journal › Article › peer-review

100 Scopus citations

Abstract

A redox-responsive quadruple hydrogen-bonding module (eDAN) has been developed. The strong binding between the reduced form and its partner (DeUG) can be significantly decreased upon oxidation but restored upon subsequent reduction. This on-off switch was successfully applied to provide reversible control of macroscopic supramolecular polymer networks.

Original language	English
Pages (from-to)	17118-17121
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	43
DOIs	https://doi.org/10.1021/ja2069278
State	Published - 2 Nov 2011
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja2069278

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title = "Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry",

abstract = "A redox-responsive quadruple hydrogen-bonding module (eDAN) has been developed. The strong binding between the reduced form and its partner (DeUG) can be significantly decreased upon oxidation but restored upon subsequent reduction. This on-off switch was successfully applied to provide reversible control of macroscopic supramolecular polymer networks.",

author = "Ying Li and Taiho Park and Quansah, {J. Kwansima} and Zimmerman, {Steven C.}",

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AU - Park, Taiho

AU - Quansah, J. Kwansima

AU - Zimmerman, Steven C.

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Y1 - 2011/11/2

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AB - A redox-responsive quadruple hydrogen-bonding module (eDAN) has been developed. The strong binding between the reduced form and its partner (DeUG) can be significantly decreased upon oxidation but restored upon subsequent reduction. This on-off switch was successfully applied to provide reversible control of macroscopic supramolecular polymer networks.

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Synthesis of a redox-responsive quadruple hydrogen-bonding unit for applications in supramolecular chemistry

Abstract

ASJC Scopus subject areas

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