Abstract
Hydrolytic removal of the core unit and cross-linking of their wedges enables dendrimers to be "cored" (see schematic representation). By internalizing the alkenes, the ring-closing metathesis reaction will "stitch" the dendritic wedges to gather intramolecularly, even at dendrimer concentrations of 10-3M. In contrast peripheral alkenes react intermolecularly at this concentration.
| Original language | English |
|---|---|
| Pages (from-to) | 1962-1966 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 10 |
| State | Published - 18 May 2001 |
| Externally published | Yes |
Keywords
- Alkenes
- Cross-linking
- Dendrimers
- Metathesis
- Oligomerization
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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