Synthesis of eight-, nine-, and ten-membered, nitrogen-containing quinone-fused heterocycles

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Abstract

A series of allylamino-, diallylamino-, homoallylamino-and bishomoallylamino naphthoquinones were synthesized. Ruthenium-mediated ring-closing metathesis (RCM) efficiently converted these substrates into novel eight-, nine-, and ten-membered quinone-fused heterocycles. Hydro-derivatives of diazacine, diazonine, and diazecine were isolated and characterized.

Original languageEnglish
Pages (from-to)239-242
Number of pages4
JournalSynthesis
Issue number2
DOIs
StatePublished - 17 Jan 2007

Keywords

  • Cyclization
  • Diazacines
  • Diazecines
  • Diazonines
  • Heterocycles
  • Naphthoquinone
  • Ring-closing metathesis

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