Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies

R. S. Chauhan; M. S. Katnori; A. M. Bhatt; P. P. Pandit; V. Brahmkhatri; Y. Torubaev; J. Wable; P. Prabhu

doi:10.1134/S003602362208006X

Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies

R. S. Chauhan, M. S. Katnori, A. M. Bhatt, P. P. Pandit, V. Brahmkhatri, Y. Torubaev, J. Wable, P. Prabhu

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1 Scopus citations

Abstract

Abstract: Two equivalents of sulphur and selenium on reaction with 1,1'-bis(diphenylphosphino)ferrocene (dppf) resulted compound of composition [Fe{C₅H₄P(E)Ph₂}₂] (E = S, Se). The latter resulted phosphine derivative on reaction with NiCl₂·6H₂O afforded an additive product [NiCl₂(dppfE₂)] (dppf = Fe{C₅H₄PPh₂}₂; E = S, Se) which on further treatment with another equivalent of [NiCl₂(dppfE₂)] followed by the addition of sodium tetraphenylborate yielded a binuclear complex [Ni₂(µ-Cl)₂(dppfE₂)](BPh₄)₂ (E = S, Se). All these complexes were characterized by elemental analysis, IR, ¹H and ³¹P{¹H} NMR spectroscopy. The molecular structure of [Fe{C₅H₄P(Se)Ph₂}₂] was determined by single crystal X-ray diffraction. The nanoparticles of complex [NiCl₂{Fe(C₅H₄P(S)Ph₂)₂}] (1a) and [NiCl₂{Fe(C₅H₄P(Se)Ph₂)₂}] (1b) was prepared through hydrothermal method. The resulting composites have further been applied for the catalytic oxidation of benzyl alcohol to aldehyde.

Original language	English
Pages (from-to)	1274-1282
Number of pages	9
Journal	Russian Journal of Inorganic Chemistry
Volume	67
Issue number	8
DOIs	https://doi.org/10.1134/S003602362208006X
State	Published - 1 Aug 2022
Externally published	Yes

Keywords

1,1'-bis(diphenylphosphino)ferrocene
NMR
nickel
polymorphism

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1134/S003602362208006X

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Chauhan, R. S., Katnori, M. S., Bhatt, A. M., Pandit, P. P., Brahmkhatri, V., Torubaev, Y., Wable, J., & Prabhu, P. (2022). Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies. Russian Journal of Inorganic Chemistry, 67(8), 1274-1282. https://doi.org/10.1134/S003602362208006X

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title = "Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies",

abstract = "Abstract: Two equivalents of sulphur and selenium on reaction with 1,1'-bis(diphenylphosphino)ferrocene (dppf) resulted compound of composition [Fe{C5H4P(E)Ph2}2] (E = S, Se). The latter resulted phosphine derivative on reaction with NiCl2·6H2O afforded an additive product [NiCl2(dppfE2)] (dppf = Fe{C5H4PPh2}2; E = S, Se) which on further treatment with another equivalent of [NiCl2(dppfE2)] followed by the addition of sodium tetraphenylborate yielded a binuclear complex [Ni2(µ-Cl)2(dppfE2)](BPh4)2 (E = S, Se). All these complexes were characterized by elemental analysis, IR, 1H and 31P{1H} NMR spectroscopy. The molecular structure of [Fe{C5H4P(Se)Ph2}2] was determined by single crystal X-ray diffraction. The nanoparticles of complex [NiCl2{Fe(C5H4P(S)Ph2)2}] (1a) and [NiCl2{Fe(C5H4P(Se)Ph2)2}] (1b) was prepared through hydrothermal method. The resulting composites have further been applied for the catalytic oxidation of benzyl alcohol to aldehyde.",

keywords = "1,1'-bis(diphenylphosphino)ferrocene, NMR, nickel, polymorphism",

author = "Chauhan, {R. S.} and Katnori, {M. S.} and Bhatt, {A. M.} and Pandit, {P. P.} and V. Brahmkhatri and Y. Torubaev and J. Wable and P. Prabhu",

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year = "2022",

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doi = "10.1134/S003602362208006X",

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T1 - Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies

AU - Chauhan, R. S.

AU - Katnori, M. S.

AU - Bhatt, A. M.

AU - Pandit, P. P.

AU - Brahmkhatri, V.

AU - Torubaev, Y.

AU - Wable, J.

AU - Prabhu, P.

PY - 2022/8/1

Y1 - 2022/8/1

N2 - Abstract: Two equivalents of sulphur and selenium on reaction with 1,1'-bis(diphenylphosphino)ferrocene (dppf) resulted compound of composition [Fe{C5H4P(E)Ph2}2] (E = S, Se). The latter resulted phosphine derivative on reaction with NiCl2·6H2O afforded an additive product [NiCl2(dppfE2)] (dppf = Fe{C5H4PPh2}2; E = S, Se) which on further treatment with another equivalent of [NiCl2(dppfE2)] followed by the addition of sodium tetraphenylborate yielded a binuclear complex [Ni2(µ-Cl)2(dppfE2)](BPh4)2 (E = S, Se). All these complexes were characterized by elemental analysis, IR, 1H and 31P{1H} NMR spectroscopy. The molecular structure of [Fe{C5H4P(Se)Ph2}2] was determined by single crystal X-ray diffraction. The nanoparticles of complex [NiCl2{Fe(C5H4P(S)Ph2)2}] (1a) and [NiCl2{Fe(C5H4P(Se)Ph2)2}] (1b) was prepared through hydrothermal method. The resulting composites have further been applied for the catalytic oxidation of benzyl alcohol to aldehyde.

AB - Abstract: Two equivalents of sulphur and selenium on reaction with 1,1'-bis(diphenylphosphino)ferrocene (dppf) resulted compound of composition [Fe{C5H4P(E)Ph2}2] (E = S, Se). The latter resulted phosphine derivative on reaction with NiCl2·6H2O afforded an additive product [NiCl2(dppfE2)] (dppf = Fe{C5H4PPh2}2; E = S, Se) which on further treatment with another equivalent of [NiCl2(dppfE2)] followed by the addition of sodium tetraphenylborate yielded a binuclear complex [Ni2(µ-Cl)2(dppfE2)](BPh4)2 (E = S, Se). All these complexes were characterized by elemental analysis, IR, 1H and 31P{1H} NMR spectroscopy. The molecular structure of [Fe{C5H4P(Se)Ph2}2] was determined by single crystal X-ray diffraction. The nanoparticles of complex [NiCl2{Fe(C5H4P(S)Ph2)2}] (1a) and [NiCl2{Fe(C5H4P(Se)Ph2)2}] (1b) was prepared through hydrothermal method. The resulting composites have further been applied for the catalytic oxidation of benzyl alcohol to aldehyde.

KW - 1,1'-bis(diphenylphosphino)ferrocene

KW - NMR

KW - nickel

KW - polymorphism

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DO - 10.1134/S003602362208006X

M3 - Article

AN - SCOPUS:85131888062

SN - 0036-0236

VL - 67

SP - 1274

EP - 1282

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 8

ER -

Synthesis of Nickel Precursors Derived from 1,1'-Bis(Diphenylchalcogenophosphoryl)Ferrocene Analogue and Their Catalytic Oxidation Reaction Studies

Abstract

Keywords

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