Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes

Vasudevan Dhayalan; Christoph Sämann; Paul Knochel

doi:10.1039/c4cc08846h

Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes

Vasudevan Dhayalan, Christoph Sämann, Paul Knochel

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl₂ and NaBH₄ in ethanol the corresponding polyfunctional secondary amines in high yields.

Original language	English
Pages (from-to)	3239-3242
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	15
DOIs	https://doi.org/10.1039/c4cc08846h
State	Published - 21 Feb 2015
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes",

abstract = "Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.",

author = "Vasudevan Dhayalan and Christoph S{\"a}mann and Paul Knochel",

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year = "2015",

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T1 - Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes

AU - Dhayalan, Vasudevan

AU - Sämann, Christoph

AU - Knochel, Paul

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/2/21

Y1 - 2015/2/21

N2 - Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.

AB - Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.

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U2 - 10.1039/c4cc08846h

DO - 10.1039/c4cc08846h

M3 - Article

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AN - SCOPUS:84929997533

SN - 1359-7345

VL - 51

SP - 3239

EP - 3242

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes

Abstract

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