Synthesis of some functional derivatives from aroxyacetylenes and aroxypropynes

G. S. Lyashenko, A. Kh Filippova, A. I. Borisova, I. D. Kalikhman, N. S. Vyazankin

Research output: Contribution to journalArticlepeer-review

Abstract

1. Some tertiary aroxyethynylcarbinols were obtained for the first time. 2. The reaction of benzaldehyde with phenoxyacetylene is stereospecific and gives the phenyl ester of trans-cinnamic acid. 3. Phenoxyacetylene adds GeCl4 to give the cis and trans adducts in a 1:1 ratio. SiCl4. under the same conditions gives only traces of the adduct.

Original languageEnglish
Pages (from-to)1946-1948
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume32
Issue number9
DOIs
StatePublished - 1 Sep 1983
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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