Synthesis of unsupported mesoporous silica interphasic films at the oil-water boundary

L. Faget; A. Berman; O. Regev

doi:10.1016/S0040-6090(00)01924-6

Synthesis of unsupported mesoporous silica interphasic films at the oil-water boundary

L. Faget
, A. Berman
, O. Regev

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Mesoporous films with cubic and hexagonal (MCM-48, 41, respectively) symmetries were synthesized at the oil-water interface. The silica precursors were segregated between oil and water phases. The film's formation was studied with small angle X-ray scattering, Brewster angle microscopy, light microscopy techniques and atomic force microscopy. A phase map depicting the aging and heating times required for the cubic phase formation was constructed. Differences in roughness between the silica-oil and silica-water interfaces were analyzed with AFM. It is speculated that the differences are indicative of the mechanism of film formation and growth.

Original language	English
Pages (from-to)	6-13
Number of pages	8
Journal	Thin Solid Films
Volume	386
Issue number	1
DOIs	https://doi.org/10.1016/S0040-6090(00)01924-6
State	Published - 1 May 2001

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1016/S0040-6090(00)01924-6

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title = "Synthesis of unsupported mesoporous silica interphasic films at the oil-water boundary",

abstract = "Mesoporous films with cubic and hexagonal (MCM-48, 41, respectively) symmetries were synthesized at the oil-water interface. The silica precursors were segregated between oil and water phases. The film's formation was studied with small angle X-ray scattering, Brewster angle microscopy, light microscopy techniques and atomic force microscopy. A phase map depicting the aging and heating times required for the cubic phase formation was constructed. Differences in roughness between the silica-oil and silica-water interfaces were analyzed with AFM. It is speculated that the differences are indicative of the mechanism of film formation and growth.",

author = "L. Faget and A. Berman and O. Regev",

note = "Funding Information: The research was supported by grants from the Israel Science Foundation, founded by The Israel Academy of Science and Humanities and the Israeli Ministry of Science and Technology. We thank Dr. J{\"u}rgen Jopp for OPIM operation.",

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doi = "10.1016/S0040-6090(00)01924-6",

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T1 - Synthesis of unsupported mesoporous silica interphasic films at the oil-water boundary

AU - Faget, L.

AU - Berman, A.

AU - Regev, O.

N1 - Funding Information: The research was supported by grants from the Israel Science Foundation, founded by The Israel Academy of Science and Humanities and the Israeli Ministry of Science and Technology. We thank Dr. Jürgen Jopp for OPIM operation.

PY - 2001/5/1

Y1 - 2001/5/1

N2 - Mesoporous films with cubic and hexagonal (MCM-48, 41, respectively) symmetries were synthesized at the oil-water interface. The silica precursors were segregated between oil and water phases. The film's formation was studied with small angle X-ray scattering, Brewster angle microscopy, light microscopy techniques and atomic force microscopy. A phase map depicting the aging and heating times required for the cubic phase formation was constructed. Differences in roughness between the silica-oil and silica-water interfaces were analyzed with AFM. It is speculated that the differences are indicative of the mechanism of film formation and growth.

AB - Mesoporous films with cubic and hexagonal (MCM-48, 41, respectively) symmetries were synthesized at the oil-water interface. The silica precursors were segregated between oil and water phases. The film's formation was studied with small angle X-ray scattering, Brewster angle microscopy, light microscopy techniques and atomic force microscopy. A phase map depicting the aging and heating times required for the cubic phase formation was constructed. Differences in roughness between the silica-oil and silica-water interfaces were analyzed with AFM. It is speculated that the differences are indicative of the mechanism of film formation and growth.

UR - https://www.scopus.com/pages/publications/0035341904

U2 - 10.1016/S0040-6090(00)01924-6

DO - 10.1016/S0040-6090(00)01924-6

M3 - Article

AN - SCOPUS:0035341904

SN - 0040-6090

VL - 386

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EP - 13

JO - Thin Solid Films

JF - Thin Solid Films

IS - 1

ER -

Synthesis of unsupported mesoporous silica interphasic films at the oil-water boundary

Abstract

ASJC Scopus subject areas

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