Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds

A. A. Pasynskii; I. V. Skabitskii; Yu V. Torubaev; Zh V. Dobrokhotova; E. V. Krasil'nikova

Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds

A. A. Pasynskii, I. V. Skabitskii, Yu V. Torubaev, Zh V. Dobrokhotova, E. V. Krasil'nikova

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The monomeric complex Cp′Cr(CO)₂S(C₅H ₄)FeCp (Cp′ = MeC₅H₄, Cp = C ₅H₅) (I) and the dimeric complex [CpCr(CO) ₂]₂[μ₂-SC₅H₄Mn(CO) ₃]₂ (II) were synthesized by the reaction of [Cp′Cr(CO)₃]₂ or [CpCr(CO)₃]₂ with metal-containing disulfides (CpFeC₅H₄) ₂S₂ or [C₅H₄Mn(CO)₃] ₂S₂, respectively. The complexes were studied by X-ray crystallography, IR spectroscopy, and differential scanning calorimetry. Complex I contains a short double bond Cr=S (2.136 Å), whereas, in II, the Cr-S bonds with two thiolate bridging groups are single (av. 2.448 Å), and a Cr-Cr bond is absent (Cr(1)-Cr(2), 3.672 Å).

Original language	English
Pages (from-to)	1197-1201
Number of pages	5
Journal	Russian Journal of Inorganic Chemistry
Volume	50
Issue number	8
State	Published - 1 Jan 2005
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{cef56f323b3849c38da70a0cbdc455a0,

title = "Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds",

abstract = "The monomeric complex Cp′Cr(CO)2S(C5H 4)FeCp (Cp′ = MeC5H4, Cp = C 5H5) (I) and the dimeric complex [CpCr(CO) 2]2[μ2-SC5H4Mn(CO) 3]2 (II) were synthesized by the reaction of [Cp′Cr(CO)3]2 or [CpCr(CO)3]2 with metal-containing disulfides (CpFeC5H4) 2S2 or [C5H4Mn(CO)3] 2S2, respectively. The complexes were studied by X-ray crystallography, IR spectroscopy, and differential scanning calorimetry. Complex I contains a short double bond Cr=S (2.136 {\AA}), whereas, in II, the Cr-S bonds with two thiolate bridging groups are single (av. 2.448 {\AA}), and a Cr-Cr bond is absent (Cr(1)-Cr(2), 3.672 {\AA}).",

author = "Pasynskii, {A. A.} and Skabitskii, {I. V.} and Torubaev, {Yu V.} and Dobrokhotova, {Zh V.} and Krasil'nikova, {E. V.}",

year = "2005",

month = jan,

day = "1",

language = "English",

volume = "50",

pages = "1197--1201",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "8",

}

Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds. / Pasynskii, A. A.; Skabitskii, I. V.; Torubaev, Yu V. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 50, No. 8, 01.01.2005, p. 1197-1201.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds

AU - Pasynskii, A. A.

AU - Skabitskii, I. V.

AU - Torubaev, Yu V.

AU - Dobrokhotova, Zh V.

AU - Krasil'nikova, E. V.

PY - 2005/1/1

Y1 - 2005/1/1

N2 - The monomeric complex Cp′Cr(CO)2S(C5H 4)FeCp (Cp′ = MeC5H4, Cp = C 5H5) (I) and the dimeric complex [CpCr(CO) 2]2[μ2-SC5H4Mn(CO) 3]2 (II) were synthesized by the reaction of [Cp′Cr(CO)3]2 or [CpCr(CO)3]2 with metal-containing disulfides (CpFeC5H4) 2S2 or [C5H4Mn(CO)3] 2S2, respectively. The complexes were studied by X-ray crystallography, IR spectroscopy, and differential scanning calorimetry. Complex I contains a short double bond Cr=S (2.136 Å), whereas, in II, the Cr-S bonds with two thiolate bridging groups are single (av. 2.448 Å), and a Cr-Cr bond is absent (Cr(1)-Cr(2), 3.672 Å).

AB - The monomeric complex Cp′Cr(CO)2S(C5H 4)FeCp (Cp′ = MeC5H4, Cp = C 5H5) (I) and the dimeric complex [CpCr(CO) 2]2[μ2-SC5H4Mn(CO) 3]2 (II) were synthesized by the reaction of [Cp′Cr(CO)3]2 or [CpCr(CO)3]2 with metal-containing disulfides (CpFeC5H4) 2S2 or [C5H4Mn(CO)3] 2S2, respectively. The complexes were studied by X-ray crystallography, IR spectroscopy, and differential scanning calorimetry. Complex I contains a short double bond Cr=S (2.136 Å), whereas, in II, the Cr-S bonds with two thiolate bridging groups are single (av. 2.448 Å), and a Cr-Cr bond is absent (Cr(1)-Cr(2), 3.672 Å).

UR - http://www.scopus.com/inward/record.url?scp=25844521151&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:25844521151

SN - 0036-0236

VL - 50

SP - 1197

EP - 1201

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 8

ER -

Synthesis, structure, and thermal decomposition of heterometallic cyclopentadienyl-dicarbonyl-chalcogenide complexes with chromium-sulfur double and single bonds

Abstract

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