Abstract
We investigate the development of electro-osmotic (Teorell) oscillations at a weakly charged microporous membrane without a preimposed transmembrane electrolyte concentration drop. This drop, necessary for the occurrence of oscillations, develops spontaneously as a result of concentration polarization in the solution layers adjacent to the membrane. A three-layer model comprising a membrane flanked by two diffusion layers is proposed and analyzed for galvano- and potentiostatic regimes of operation.
Original language | English |
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Article number | 022305 |
Journal | Physical Review E |
Volume | 92 |
Issue number | 2 |
DOIs | |
State | Published - 13 Aug 2015 |
ASJC Scopus subject areas
- Statistical and Nonlinear Physics
- Statistics and Probability
- Condensed Matter Physics