The adsorption of H2O vs O2 on beryllium

S. Zalkind, M. Polak, N. Shamir

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

The adsorption mechanism and initial oxidation of sputtered beryllium exposed to H2O and to O2 were studied using a combination of the DRS, AES and XPS techniques. For both cases, the "clustering" Langmuir type mechanism was found to fit the adsorption kinetics. The initial sticking coefficients, estimated from these fits, are S0(H2O) ≈ 1 S0(O2) ≈ 0.07. Oxide islands, ∼ 3 monolayers thick, are formed in both cases, spreading laterally till a full layer is formed. For O2 the oxidation stops at this stage, while for H2O it continues at a lower rate, reaching a saturation level of about six monolayers. Observation of significant broadening of the AES O KVV peak in the stage of thickness growth for the H2O exposure, and DRS H depth profiling indicate that hydrogen is trapped in the oxide matrix. Possible hydrogen-enhanced-diffusion of ions through the oxide seems to enable the further growth.

Original languageEnglish
Pages (from-to)318-327
Number of pages10
JournalSurface Science
Volume385
Issue number2-3
DOIs
StatePublished - 10 Aug 1997

Keywords

  • Adsorption kinetics
  • Auger electron spectroscopy
  • Beryllium
  • Oxidation
  • Oxygen
  • Water

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'The adsorption of H2O vs O2 on beryllium'. Together they form a unique fingerprint.

Cite this