The composition dependence of glass transition properties

J. M. Gordon; G. B. Rouse; J. H. Gibbs; W. M. Risen

doi:10.1063/1.433798

The composition dependence of glass transition properties

J. M. Gordon, G. B. Rouse, J. H. Gibbs, W. M. Risen

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171 Scopus citations

Abstract

The configurational entropy theory of glass formation is used to derive the composition dependence of the glass transition temperature (T_g) and of supercooled liquid transport properties for binary mixtures which obey the laws of regular solutions. The relations between expressions derived subject to specified approximations and known empirical equations are shown, and the parameters of the latter are thereby identified with defined measurable quantities. The predicted composition dependence of T_g is compared with experimental data from binary mixtures with satisfactory agreement.

Original language	English
Pages (from-to)	4971-4976
Number of pages	6
Journal	Journal of Chemical Physics
Volume	66
Issue number	11
DOIs	https://doi.org/10.1063/1.433798
State	Published - 1 Jan 1977
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The configurational entropy theory of glass formation is used to derive the composition dependence of the glass transition temperature (Tg) and of supercooled liquid transport properties for binary mixtures which obey the laws of regular solutions. The relations between expressions derived subject to specified approximations and known empirical equations are shown, and the parameters of the latter are thereby identified with defined measurable quantities. The predicted composition dependence of Tg is compared with experimental data from binary mixtures with satisfactory agreement.",

author = "Gordon, {J. M.} and Rouse, {G. B.} and Gibbs, {J. H.} and Risen, {W. M.}",

year = "1977",

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AU - Gibbs, J. H.

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N2 - The configurational entropy theory of glass formation is used to derive the composition dependence of the glass transition temperature (Tg) and of supercooled liquid transport properties for binary mixtures which obey the laws of regular solutions. The relations between expressions derived subject to specified approximations and known empirical equations are shown, and the parameters of the latter are thereby identified with defined measurable quantities. The predicted composition dependence of Tg is compared with experimental data from binary mixtures with satisfactory agreement.

AB - The configurational entropy theory of glass formation is used to derive the composition dependence of the glass transition temperature (Tg) and of supercooled liquid transport properties for binary mixtures which obey the laws of regular solutions. The relations between expressions derived subject to specified approximations and known empirical equations are shown, and the parameters of the latter are thereby identified with defined measurable quantities. The predicted composition dependence of Tg is compared with experimental data from binary mixtures with satisfactory agreement.

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The composition dependence of glass transition properties

Abstract

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