The donor-acceptor and charge alternation principle and the electrochemical oxidation and reduction of disubstituted benzenes

James Y. Becker; Joseph Klein

doi:10.1016/S0040-4020(01)81737-3

The donor-acceptor and charge alternation principle and the electrochemical oxidation and reduction of disubstituted benzenes

James Y. Becker, Joseph Klein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The charge alternation principle correlates nicely with the redox potential of disubstituted benzenes, and predicts that the least thermodynamically stable isomer in a given series of ortho-, para-, and meta- disubstituted benzenes, is also the easiest to oxidize or reduce, electrochemically.

Original language	English
Pages (from-to)	2289-2292
Number of pages	4
Journal	Tetrahedron
Volume	44
Issue number	8
DOIs	https://doi.org/10.1016/S0040-4020(01)81737-3
State	Published - 1 Jan 1988

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4020(01)81737-3

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title = "The donor-acceptor and charge alternation principle and the electrochemical oxidation and reduction of disubstituted benzenes",

abstract = "The charge alternation principle correlates nicely with the redox potential of disubstituted benzenes, and predicts that the least thermodynamically stable isomer in a given series of ortho-, para-, and meta- disubstituted benzenes, is also the easiest to oxidize or reduce, electrochemically.",

author = "Becker, \{James Y.\} and Joseph Klein",

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T1 - The donor-acceptor and charge alternation principle and the electrochemical oxidation and reduction of disubstituted benzenes

AU - Becker, James Y.

AU - Klein, Joseph

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The charge alternation principle correlates nicely with the redox potential of disubstituted benzenes, and predicts that the least thermodynamically stable isomer in a given series of ortho-, para-, and meta- disubstituted benzenes, is also the easiest to oxidize or reduce, electrochemically.

AB - The charge alternation principle correlates nicely with the redox potential of disubstituted benzenes, and predicts that the least thermodynamically stable isomer in a given series of ortho-, para-, and meta- disubstituted benzenes, is also the easiest to oxidize or reduce, electrochemically.

UR - https://www.scopus.com/pages/publications/6344229521

U2 - 10.1016/S0040-4020(01)81737-3

DO - 10.1016/S0040-4020(01)81737-3

M3 - Article

AN - SCOPUS:6344229521

SN - 0040-4020

VL - 44

SP - 2289

EP - 2292

JO - Tetrahedron

JF - Tetrahedron

IS - 8

ER -

The donor-acceptor and charge alternation principle and the electrochemical oxidation and reduction of disubstituted benzenes

Abstract

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