The efficacy of various scavengers in the study of hot chlorine reactions

Zeev B. Alfassi; Saadia Amiel

doi:10.1524/ract.1971.15.4.201

The efficacy of various scavengers in the study of hot chlorine reactions

Zeev B. Alfassi, Saadia Amiel

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8 Scopus citations

Abstract

Various scavengers used in the study of hot halogen reactions were tested for the system 38Cl + CH3Cl → CH338Cl + Cl, where the hot chlorine originated from neutron capture. It was found that a 1 to 2 percent concentration of Br2 or I2 was an effective scavenger and removed radicals, thermal atoms and ions. Other scavengers which were tried required a mixture of a radical scavenger and a thermal halogen scavenger to obtain the true “hot” reaction yield. A value of 3.4 ± 0.25 percent was obtained for the yield of the above hot atom reaction.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Radiochimica Acta
Volume	15
Issue number	4
DOIs	https://doi.org/10.1524/ract.1971.15.4.201
State	Published - 1 Jan 1971
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1524/ract.1971.15.4.201

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abstract = "Various scavengers used in the study of hot halogen reactions were tested for the system 38Cl + CH3Cl → CH338Cl + Cl, where the hot chlorine originated from neutron capture. It was found that a 1 to 2 percent concentration of Br2 or I2 was an effective scavenger and removed radicals, thermal atoms and ions. Other scavengers which were tried required a mixture of a radical scavenger and a thermal halogen scavenger to obtain the true “hot” reaction yield. A value of 3.4 ± 0.25 percent was obtained for the yield of the above hot atom reaction.",

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AU - Amiel, Saadia

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N2 - Various scavengers used in the study of hot halogen reactions were tested for the system 38Cl + CH3Cl → CH338Cl + Cl, where the hot chlorine originated from neutron capture. It was found that a 1 to 2 percent concentration of Br2 or I2 was an effective scavenger and removed radicals, thermal atoms and ions. Other scavengers which were tried required a mixture of a radical scavenger and a thermal halogen scavenger to obtain the true “hot” reaction yield. A value of 3.4 ± 0.25 percent was obtained for the yield of the above hot atom reaction.

AB - Various scavengers used in the study of hot halogen reactions were tested for the system 38Cl + CH3Cl → CH338Cl + Cl, where the hot chlorine originated from neutron capture. It was found that a 1 to 2 percent concentration of Br2 or I2 was an effective scavenger and removed radicals, thermal atoms and ions. Other scavengers which were tried required a mixture of a radical scavenger and a thermal halogen scavenger to obtain the true “hot” reaction yield. A value of 3.4 ± 0.25 percent was obtained for the yield of the above hot atom reaction.

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The efficacy of various scavengers in the study of hot chlorine reactions

Abstract

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