The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Esther Zeigerson; Gregory Ginzburg; Louis J. Kirschenbaum; Dan Meyerstein

doi:10.1016/S0022-0728(81)80472-X

The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Esther Zeigerson
, Gregory Ginzburg
, Louis J. Kirschenbaum
, Dan Meyerstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

Original language	English
Pages (from-to)	113-126
Number of pages	14
Journal	Journal of Electroanalytical Chemistry
Volume	127
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-0728(81)80472-X
State	Published - 9 Oct 1981

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/S0022-0728(81)80472-X

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@article{4bf34055c9b9427894dedc1b6da7367e,

title = "The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions",

abstract = "The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.",

author = "Esther Zeigerson and Gregory Ginzburg and Kirschenbaum, \{Louis J.\} and Dan Meyerstein",

year = "1981",

month = oct,

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doi = "10.1016/S0022-0728(81)80472-X",

language = "English",

volume = "127",

pages = "113--126",

journal = "Journal of Electroanalytical Chemistry",

issn = "0022-0728",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

AU - Zeigerson, Esther

AU - Ginzburg, Gregory

AU - Kirschenbaum, Louis J.

AU - Meyerstein, Dan

PY - 1981/10/9

Y1 - 1981/10/9

N2 - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

AB - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

UR - https://www.scopus.com/pages/publications/2542549068

U2 - 10.1016/S0022-0728(81)80472-X

DO - 10.1016/S0022-0728(81)80472-X

M3 - Article

AN - SCOPUS:2542549068

SN - 0022-0728

VL - 127

SP - 113

EP - 126

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-3

ER -

The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Abstract

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