The electrochemistry of square planar macrocyclic nickel complexes and the reaction of Ni(I) with alkyl bromides: Nickel tetraamine complexes

J. Y. Becker; J. B. Kerr; D. Pletcher; R. Rosas

doi:10.1016/S0022-0728(81)80452-4

The electrochemistry of square planar macrocyclic nickel complexes and the reaction of Ni(I) with alkyl bromides: Nickel tetraamine complexes

J. Y. Becker, J. B. Kerr, D. Pletcher, R. Rosas

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Abstract

The electrochemistry of nine cyclic tetraamine complexes of Ni(II) in aprotic solvents has been investigated. It is shown that all form Ni(I) complexes which react with alkyl bromides, but only with some complexes are the reactions catalytic with respect to the nickel complex. The dependence of the electrochemical parameters and the mechanism and kinetics of the coupled chemical reactions on the structure of the ligands are discussed.

Original language	English
Pages (from-to)	87-99
Number of pages	13
Journal	Journal of Electroanalytical Chemistry
Volume	117
Issue number	1
DOIs	https://doi.org/10.1016/S0022-0728(81)80452-4
State	Published - 10 Jan 1981
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/S0022-0728(81)80452-4

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abstract = "The electrochemistry of nine cyclic tetraamine complexes of Ni(II) in aprotic solvents has been investigated. It is shown that all form Ni(I) complexes which react with alkyl bromides, but only with some complexes are the reactions catalytic with respect to the nickel complex. The dependence of the electrochemical parameters and the mechanism and kinetics of the coupled chemical reactions on the structure of the ligands are discussed.",

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T1 - The electrochemistry of square planar macrocyclic nickel complexes and the reaction of Ni(I) with alkyl bromides

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AU - Becker, J. Y.

AU - Kerr, J. B.

AU - Pletcher, D.

AU - Rosas, R.

PY - 1981/1/10

Y1 - 1981/1/10

N2 - The electrochemistry of nine cyclic tetraamine complexes of Ni(II) in aprotic solvents has been investigated. It is shown that all form Ni(I) complexes which react with alkyl bromides, but only with some complexes are the reactions catalytic with respect to the nickel complex. The dependence of the electrochemical parameters and the mechanism and kinetics of the coupled chemical reactions on the structure of the ligands are discussed.

AB - The electrochemistry of nine cyclic tetraamine complexes of Ni(II) in aprotic solvents has been investigated. It is shown that all form Ni(I) complexes which react with alkyl bromides, but only with some complexes are the reactions catalytic with respect to the nickel complex. The dependence of the electrochemical parameters and the mechanism and kinetics of the coupled chemical reactions on the structure of the ligands are discussed.

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DO - 10.1016/S0022-0728(81)80452-4

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AN - SCOPUS:0002075097

SN - 0022-0728

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The electrochemistry of square planar macrocyclic nickel complexes and the reaction of Ni(I) with alkyl bromides: Nickel tetraamine complexes

Abstract

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