The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Michael Bendikov; Victoria Kravchenko; Yitzhak Apeloig; James Y. Becker

doi:10.1021/om0341909

The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Michael Bendikov
, Victoria Kravchenko
, Yitzhak Apeloig
, James Y. Becker

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe₂Si)(Me₃-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.

Original language	English
Pages (from-to)	921-923
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	4
DOIs	https://doi.org/10.1021/om0341909
State	Published - 16 Feb 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0341909

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title = "The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors",

abstract = "The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.",

author = "Michael Bendikov and Victoria Kravchenko and Yitzhak Apeloig and Becker, \{James Y.\}",

year = "2004",

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doi = "10.1021/om0341909",

language = "English",

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journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

AU - Bendikov, Michael

AU - Kravchenko, Victoria

AU - Apeloig, Yitzhak

AU - Becker, James Y.

PY - 2004/2/16

Y1 - 2004/2/16

N2 - The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.

AB - The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.

UR - https://www.scopus.com/pages/publications/1442285088

U2 - 10.1021/om0341909

DO - 10.1021/om0341909

M3 - Article

AN - SCOPUS:1442285088

SN - 0276-7333

VL - 23

SP - 921

EP - 923

JO - Organometallics

JF - Organometallics

IS - 4

ER -

The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Abstract

ASJC Scopus subject areas

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