The hyperfine structure in the electronic A 2E″ ← X 2E′ system of the pseudorotating lithium trimer

W. Meyer, M. Keil, A. Kudell, M. A. Baig, J. Zhu, W. Demtröder

Research output: Contribution to journalArticlepeer-review

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Abstract

A detailed analysis of the hyperfine structure (hfs) in free Li3 clusters was carried out based on ab initio calculated electron spin densities. It was found that the hyperfine splittings in high-resolution spectra of the A←X electronic transition band of the clusters give complete information on the electron spin densities at the nuclei for vibronic states.

Original languageEnglish
Pages (from-to)2590-2602
Number of pages13
JournalJournal of Chemical Physics
Volume115
Issue number6
DOIs
StatePublished - 8 Aug 2001
Externally publishedYes

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