The importance of ground-state vibronic mixing in molecular Raman scattering

Benjamin Scharf, Yehuda B. Band

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

We consider Albrecht's theory for Raman scattering of fundamentals in the far and pre-resonance regions. Destructive interferences inherent to the A and B terms augment the conventionally suppressed C term dramatically. Raman excitation profiles for the ν1(a1g) and ν6(e2g fundamentals in benzene can be well fitted with theoretical C-term profiles involving the 1E1u(π-π*) state at 1800 A.

Original languageEnglish
Pages (from-to)383-389
Number of pages7
JournalChemical Physics Letters
Volume91
Issue number5
DOIs
StatePublished - 24 Sep 1982

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