The influence of TiN on cosputtered (Tin + Si) blanket film

Joshua Pelleg, Y. Shor

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

X-ray diffraction, transmission electron microscopy and Auger spectroscopy were used to study the formation of TiSi2 from a cosputtered (Ti + Si) film with and without TiN capping. In all cases, a metal rich silicide identified as Ti5Si3, was the first phase to form from the amorphous (Ti + Si) regardless if a TiN overlayer was or was not present. At temperatures of 923 K and below it only Ti5Si3 was observed in all specimens. C54 TiSi2 formation is enhanced in specimens having a TiN capping and its formation occurs at lower temperatures and at a faster rate at some appropriate temperature than in specimens without TiN. The effect of tensile stress induced by the TiN layer is suggested as the reason of C54 TiSi2 formation.

Original languageEnglish
Pages (from-to)258-266
Number of pages9
JournalThin Solid Films
Volume424
Issue number2
DOIs
StatePublished - 31 Jan 2003

Keywords

  • C54 TiSi
  • Cosputtered (Ti + Si)
  • TiN
  • TiSi

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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