The infrared absorption spectra of normal and18O-labelled triphenylarsine oxide

J. Bernstein; M. Halmann; S. Pinchas; David Samuel

The infrared absorption spectra of normal and¹⁸O-labelled triphenylarsine oxide

J. Bernstein, M. Halmann, S. Pinchas, David Samuel

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Abstract

The spectra of normal and ca. 90 atom % triphenylarsine [ ¹⁸O]oxicle have been measured in the 3700-420 cm.^-1 region, for chloroform, bromoform, and acetonitrile solutions, and assignment of the observed bands made. The As=¹⁶O band at 880 cm.^-1 appears to be the only one which is shifted in the case of the labelled oxide, and the observed shift (40 cm.^-1) is in agreement with that expected from theory (41 cm.^-1). The relative integrated absorption intensity of the As=¹⁸O band is only 82% of that for the As=¹⁶O band, while the expected value is as high as 91%.

Original language	English
Pages (from-to)	810-820
Number of pages	11
Journal	Journal of the Chemical Society
State	Published - 1 Dec 1964
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "The infrared absorption spectra of normal and18O-labelled triphenylarsine oxide",

abstract = "The spectra of normal and ca. 90 atom % triphenylarsine [ 18O]oxicle have been measured in the 3700-420 cm.-1 region, for chloroform, bromoform, and acetonitrile solutions, and assignment of the observed bands made. The As=16O band at 880 cm.-1 appears to be the only one which is shifted in the case of the labelled oxide, and the observed shift (40 cm.-1) is in agreement with that expected from theory (41 cm.-1). The relative integrated absorption intensity of the As=18O band is only 82% of that for the As=16O band, while the expected value is as high as 91%.",

author = "J. Bernstein and M. Halmann and S. Pinchas and David Samuel",

year = "1964",

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language = "English",

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journal = "Journal of the Chemical Society",

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T1 - The infrared absorption spectra of normal and18O-labelled triphenylarsine oxide

AU - Bernstein, J.

AU - Halmann, M.

AU - Pinchas, S.

AU - Samuel, David

PY - 1964/12/1

Y1 - 1964/12/1

N2 - The spectra of normal and ca. 90 atom % triphenylarsine [ 18O]oxicle have been measured in the 3700-420 cm.-1 region, for chloroform, bromoform, and acetonitrile solutions, and assignment of the observed bands made. The As=16O band at 880 cm.-1 appears to be the only one which is shifted in the case of the labelled oxide, and the observed shift (40 cm.-1) is in agreement with that expected from theory (41 cm.-1). The relative integrated absorption intensity of the As=18O band is only 82% of that for the As=16O band, while the expected value is as high as 91%.

AB - The spectra of normal and ca. 90 atom % triphenylarsine [ 18O]oxicle have been measured in the 3700-420 cm.-1 region, for chloroform, bromoform, and acetonitrile solutions, and assignment of the observed bands made. The As=16O band at 880 cm.-1 appears to be the only one which is shifted in the case of the labelled oxide, and the observed shift (40 cm.-1) is in agreement with that expected from theory (41 cm.-1). The relative integrated absorption intensity of the As=18O band is only 82% of that for the As=16O band, while the expected value is as high as 91%.

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M3 - Article

AN - SCOPUS:37049040375

SN - 0368-1769

SP - 810

EP - 820

JO - Journal of the Chemical Society

JF - Journal of the Chemical Society

ER -

The infrared absorption spectra of normal and¹⁸O-labelled triphenylarsine oxide

Abstract

ASJC Scopus subject areas

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