The kinetics of radiation induced hydrogen abstraction by CCl3 radicals in the liquid phase: Cyclanes

Zeev B. Alfassi; Liviu Feldman

doi:10.1002/kin.550130602

The kinetics of radiation induced hydrogen abstraction by CCl₃ radicals in the liquid phase: Cyclanes

Zeev B. Alfassi, Liviu Feldman

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The kinetics of gamma‐radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order cC₆H₁₂ > cC₁₂H₂₄ > cC₈H₁₆, which was explained as due to their ring strain which has the same order. The following log k₁ was obtained using the known Arrhenius parameters for CCl₃ radical recombination: (Formula Presented.)

Original language	English
Pages (from-to)	517-526
Number of pages	10
Journal	International Journal of Chemical Kinetics
Volume	13
Issue number	6
DOIs	https://doi.org/10.1002/kin.550130602
State	Published - 1 Jan 1981

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "The kinetics of radiation induced hydrogen abstraction by CCl3 radicals in the liquid phase: Cyclanes",

abstract = "The kinetics of gamma‐radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order cC6H12 > cC12H24 > cC8H16, which was explained as due to their ring strain which has the same order. The following log k1 was obtained using the known Arrhenius parameters for CCl3 radical recombination: (Formula Presented.)",

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N2 - The kinetics of gamma‐radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order cC6H12 > cC12H24 > cC8H16, which was explained as due to their ring strain which has the same order. The following log k1 was obtained using the known Arrhenius parameters for CCl3 radical recombination: (Formula Presented.)

AB - The kinetics of gamma‐radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order cC6H12 > cC12H24 > cC8H16, which was explained as due to their ring strain which has the same order. The following log k1 was obtained using the known Arrhenius parameters for CCl3 radical recombination: (Formula Presented.)

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The kinetics of radiation induced hydrogen abstraction by CCl₃ radicals in the liquid phase: Cyclanes

Abstract

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