The liquid‐phase reaction of CCl3 radicals with primary alcohols

Liviu Feldman; Zeev B. Alfassi

doi:10.1002/kin.550140608

The liquid‐phase reaction of CCl₃ radicals with primary alcohols

Liviu Feldman, Zeev B. Alfassi

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

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Abstract

The kinetics of gamma‐radiation‐induced free‐radical reactions in carbon tetrachloride solutions of ethanol and n‐pentanol were studied in the range of 0.05–0.80M and 25–170°C. The rate constant for the reaction (Formula Presented.) was found as (Formula Presented.) The activation energy is larger by 0.8 kcal/mol than for secondary alcohols, while the A₁ factors are about the same.

Original language	English
Pages (from-to)	659-668
Number of pages	10
Journal	International Journal of Chemical Kinetics
Volume	14
Issue number	6
DOIs	https://doi.org/10.1002/kin.550140608
State	Published - 1 Jan 1982

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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AB - The kinetics of gamma‐radiation‐induced free‐radical reactions in carbon tetrachloride solutions of ethanol and n‐pentanol were studied in the range of 0.05–0.80M and 25–170°C. The rate constant for the reaction (Formula Presented.) was found as (Formula Presented.) The activation energy is larger by 0.8 kcal/mol than for secondary alcohols, while the A1 factors are about the same.

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The liquid‐phase reaction of CCl₃ radicals with primary alcohols

Abstract

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