TY - JOUR
T1 - The oxidation of nickelII (1,4,8,11-tetraazacyclotetradecane) by hydroperoxyl radicals
T2 - A pulse radiolysis study
AU - Meshulam, Avraham
AU - Cohen, Haim
AU - Meyerstein, Dan
N1 - Funding Information:
This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. D.M. wishes to express his thanks to Mrs Irene Evens for her ongoing interest and support.
PY - 1998/5/15
Y1 - 1998/5/15
N2 - Hydroperoxyl radicals oxidize NiL2+ in solutions containing SO42- and H2PO4- to (LNiIII(SO4)2) and (LNiIII(H2PO4)2) +. The mechanism of these processes involves mainly the following reactions: NiL2+ + HO2•⇆L(H2O)NiIII(HO 2-)2+ L(H2O)NiIII(HO2-)2+ + X- ⇆ LNiIII(X-)(HO2-) + LNiIII(X-)(HO2-)+ + X- + H3O+ → LNiIII(X-)2+ + H2O2 This mechanism differs from that observed for the analogous oxidation of Ni(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)2,4. The difference in the mechanisms stems from the difference in the redox potentials of the complexes.
AB - Hydroperoxyl radicals oxidize NiL2+ in solutions containing SO42- and H2PO4- to (LNiIII(SO4)2) and (LNiIII(H2PO4)2) +. The mechanism of these processes involves mainly the following reactions: NiL2+ + HO2•⇆L(H2O)NiIII(HO 2-)2+ L(H2O)NiIII(HO2-)2+ + X- ⇆ LNiIII(X-)(HO2-) + LNiIII(X-)(HO2-)+ + X- + H3O+ → LNiIII(X-)2+ + H2O2 This mechanism differs from that observed for the analogous oxidation of Ni(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)2,4. The difference in the mechanisms stems from the difference in the redox potentials of the complexes.
KW - Azamacrocycle complexes
KW - Hydroperoxyl radicals
KW - Nickel complexes
KW - Oxidation
UR - http://www.scopus.com/inward/record.url?scp=0041193034&partnerID=8YFLogxK
U2 - 10.1016/s0020-1693(97)05968-9
DO - 10.1016/s0020-1693(97)05968-9
M3 - Article
AN - SCOPUS:0041193034
SN - 0020-1693
VL - 273
SP - 266
EP - 269
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1-2
ER -