The rate constant for combination of a CCl3 radical with cyclohexyl or n‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer

Zeev B. Alfassi

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl3 radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.

Original languageEnglish
Pages (from-to)217-223
Number of pages7
JournalInternational Journal of Chemical Kinetics
Volume12
Issue number4
DOIs
StatePublished - 1 Jan 1980

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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