The rate constant for combination of a CCl3 radical with cyclohexyl or n‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer

Zeev B. Alfassi

doi:10.1002/kin.550120402

The rate constant for combination of a CCl₃ radical with cyclohexyl or n‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer

Zeev B. Alfassi

Unit of Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl₃ radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.

Original language	English
Pages (from-to)	217-223
Number of pages	7
Journal	International Journal of Chemical Kinetics
Volume	12
Issue number	4
DOIs	https://doi.org/10.1002/kin.550120402
State	Published - 1 Jan 1980

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/kin.550120402

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title = "The rate constant for combination of a CCl3 radical with cyclohexyl or n‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer",

abstract = "The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl3 radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.",

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N2 - The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl3 radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.

AB - The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl3 radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.

UR - https://www.scopus.com/pages/publications/84985326835

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DO - 10.1002/kin.550120402

M3 - Article

AN - SCOPUS:84985326835

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JF - International Journal of Chemical Kinetics

IS - 4

ER -

The rate constant for combination of a CCl₃ radical with cyclohexyl or n‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer

Abstract

ASJC Scopus subject areas

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