Abstract
Alkylcopper compounds RCu react with salt-free cuprous acetylides R′CCCu to give disubstituted acetylenes, R′CCR, the products of unsymmetrical coupling. Conjugated acetylenic acids react with methylcopper in the absence of salts to give similar products resulting from decarboxylation followed by coupling.
Original language | English |
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Pages (from-to) | 467-471 |
Number of pages | 5 |
Journal | Journal of Organometallic Chemistry |
Volume | 67 |
Issue number | 3 |
DOIs | |
State | Published - 19 Mar 1974 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry