The reactivity game: Theoretical predictions for heavy atom tunneling in adamantyl and related carbenes

Keyphrases

• Game Analysis 100%
• Carbenes 100%
• Heavy-atom Tunneling 100%
• Adamantyl 100%
• Barrier Height 80%
• Quantum Tunneling 40%
• Adamantane 40%
• Cryogenic Temperature 20%
• C-C Bond 20%
• Tunneling 20%
• Experimental Predictions 20%
• Experimental Values 20%
• Carbon Atom 20%
• Delicate Balance 20%
• Kinetic Isotope Effect 20%
• Atom Tunneling 20%
• Ring Expansion 20%
• Small Curvature Tunneling 20%
• Thermal Mechanism 20%
• Physical Limits 20%
• Stable Carbenes 20%
• Tinkering 20%
• Bond Strain 20%

Chemistry

• Carbene 100%
• Adamantane 33%
• Hydrogen 16%
• Carbon Atom 16%
• Rate Constant 16%
• Kinetic Isotope Effect 16%
• Ring Expansion 16%