The relation between lyotropic and spectroscopic properties of anions in solution

Dan Meyerstein; Avner Treinin

doi:10.1021/j100809a017

The relation between lyotropic and spectroscopic properties of anions in solution

Dan Meyerstein, Avner Treinin

Research output: Contribution to journal › Article › peer-review

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Abstract

Anionic effects on the charge-transfer absorption band of I^- were studied in detail. The results indicate that the spectroscopic effects of the added anions depend mainly on their power to desolvate the test ion I^-. Thus a correlation is presented between the spectroscopic and lyotropic series, with the halides forming a separate group. The mechanism of the anionic effect on this type of spectra (C.T.T.S. spectra) is discussed and some evidence is brought in favor of the continuous medium approximation which involves the ionic cavity radius as a variable.

Original language	English
Pages (from-to)	446-450
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	66
Issue number	3
DOIs	https://doi.org/10.1021/j100809a017
State	Published - 1 Jan 1962
Externally published	Yes

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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abstract = "Anionic effects on the charge-transfer absorption band of I- were studied in detail. The results indicate that the spectroscopic effects of the added anions depend mainly on their power to desolvate the test ion I-. Thus a correlation is presented between the spectroscopic and lyotropic series, with the halides forming a separate group. The mechanism of the anionic effect on this type of spectra (C.T.T.S. spectra) is discussed and some evidence is brought in favor of the continuous medium approximation which involves the ionic cavity radius as a variable.",

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AU - Treinin, Avner

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AB - Anionic effects on the charge-transfer absorption band of I- were studied in detail. The results indicate that the spectroscopic effects of the added anions depend mainly on their power to desolvate the test ion I-. Thus a correlation is presented between the spectroscopic and lyotropic series, with the halides forming a separate group. The mechanism of the anionic effect on this type of spectra (C.T.T.S. spectra) is discussed and some evidence is brought in favor of the continuous medium approximation which involves the ionic cavity radius as a variable.

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The relation between lyotropic and spectroscopic properties of anions in solution

Abstract

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