The shortened transition metal-tellurium bonds in organometallic clusters

Alexander A. Pasynskii; Yuri V. Torubaev; Vladimir N. Grigor'Ev; Anton I. Blokhin; Max Herberhold; Pradeep Mathur

doi:10.1007/s10876-008-0227-0

The shortened transition metal-tellurium bonds in organometallic clusters

Alexander A. Pasynskii, Yuri V. Torubaev, Vladimir N. Grigor'Ev, Anton I. Blokhin, Max Herberhold, Pradeep Mathur

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes of organometallic compounds: (1) formally electron-deficient species with additional donor-acceptor interaction between Te lone pairs and half-occupied d-orbitals of M; (2) formally electron-saturated species having additional dative interaction between M lone pairs and LUMO of Te. These compounds could be prepared by two main methods: (a) interaction of [CpMn(CO)₂PhC(O)^-]Li⁺ with Te proceeds via formation of intermediate {[CpMn(CO)₂]₂Te}^2- which is further transformed into binuclear complex [CpMn(CO)₂] ₂Te(CH₂Ph)₂ or into trinuclear ditelluride cluster [CpMn(CO)₂]₃Te₂ on one hand or to mixed-metal monotelluride clusters [CpMn(CO)₂]₂TeM(CO) ₅ on another hand. (b) treatment of Fe(CO)₅, CpMn(CO) ₂(THF) or Me₄C₄Co(CO)₂I with [PhTeI]₄, PhTeI₃ or PhTeI₂HC = CPhI results in different PhTeI-containing complexes of Fe, Mn or Co. The molecular structures of all new compounds were studied by means of X-ray diffraction analyses and the mechanism of M-Te bond shortening is discussed.

Original language	English
Pages (from-to)	193-204
Number of pages	12
Journal	Journal of Cluster Science
Volume	20
Issue number	1
DOIs	https://doi.org/10.1007/s10876-008-0227-0
State	Published - 1 Mar 2009
Externally published	Yes

Keywords

Chromium
Cobalt
Cyclopentadienyl complexes
Iron
Manganese
Metal carbonyls
Metal tellurides
Mixed-metal clusters
Tungsten
X-ray analyses

ASJC Scopus subject areas

Biochemistry
General Chemistry
General Materials Science
Condensed Matter Physics

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10.1007/s10876-008-0227-0

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@article{562d344a0d4f45ae93779fc6cbdaacbe,

title = "The shortened transition metal-tellurium bonds in organometallic clusters",

abstract = "The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes of organometallic compounds: (1) formally electron-deficient species with additional donor-acceptor interaction between Te lone pairs and half-occupied d-orbitals of M; (2) formally electron-saturated species having additional dative interaction between M lone pairs and LUMO of Te. These compounds could be prepared by two main methods: (a) interaction of [CpMn(CO)2PhC(O)-]Li+ with Te proceeds via formation of intermediate \{[CpMn(CO)2]2Te\}2- which is further transformed into binuclear complex [CpMn(CO)2] 2Te(CH2Ph)2 or into trinuclear ditelluride cluster [CpMn(CO)2]3Te2 on one hand or to mixed-metal monotelluride clusters [CpMn(CO)2]2TeM(CO) 5 on another hand. (b) treatment of Fe(CO)5, CpMn(CO) 2(THF) or Me4C4Co(CO)2I with [PhTeI]4, PhTeI3 or PhTeI2HC = CPhI results in different PhTeI-containing complexes of Fe, Mn or Co. The molecular structures of all new compounds were studied by means of X-ray diffraction analyses and the mechanism of M-Te bond shortening is discussed.",

keywords = "Chromium, Cobalt, Cyclopentadienyl complexes, Iron, Manganese, Metal carbonyls, Metal tellurides, Mixed-metal clusters, Tungsten, X-ray analyses",

author = "Pasynskii, \{Alexander A.\} and Torubaev, \{Yuri V.\} and Grigor'Ev, \{Vladimir N.\} and Blokhin, \{Anton I.\} and Max Herberhold and Pradeep Mathur",

note = "Funding Information: Acknowledgments The authors thank Dr. K.A. Lyssenko (A.N. Nesmeyanov Institute of Organoel-ement Compounds, RAS) for X-ray diffraction study and Russian Foundation of Fundamental Research (grant §06-03-32891), District of Chemistry and Materials Sciences of RAS (grant OKh 1.4) and Presidium of RAS (grant 8P15) for financial support.",

year = "2009",

month = mar,

day = "1",

doi = "10.1007/s10876-008-0227-0",

language = "English",

volume = "20",

pages = "193--204",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - The shortened transition metal-tellurium bonds in organometallic clusters

AU - Pasynskii, Alexander A.

AU - Torubaev, Yuri V.

AU - Grigor'Ev, Vladimir N.

AU - Blokhin, Anton I.

AU - Herberhold, Max

AU - Mathur, Pradeep

N1 - Funding Information: Acknowledgments The authors thank Dr. K.A. Lyssenko (A.N. Nesmeyanov Institute of Organoel-ement Compounds, RAS) for X-ray diffraction study and Russian Foundation of Fundamental Research (grant §06-03-32891), District of Chemistry and Materials Sciences of RAS (grant OKh 1.4) and Presidium of RAS (grant 8P15) for financial support.

PY - 2009/3/1

Y1 - 2009/3/1

N2 - The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes of organometallic compounds: (1) formally electron-deficient species with additional donor-acceptor interaction between Te lone pairs and half-occupied d-orbitals of M; (2) formally electron-saturated species having additional dative interaction between M lone pairs and LUMO of Te. These compounds could be prepared by two main methods: (a) interaction of [CpMn(CO)2PhC(O)-]Li+ with Te proceeds via formation of intermediate {[CpMn(CO)2]2Te}2- which is further transformed into binuclear complex [CpMn(CO)2] 2Te(CH2Ph)2 or into trinuclear ditelluride cluster [CpMn(CO)2]3Te2 on one hand or to mixed-metal monotelluride clusters [CpMn(CO)2]2TeM(CO) 5 on another hand. (b) treatment of Fe(CO)5, CpMn(CO) 2(THF) or Me4C4Co(CO)2I with [PhTeI]4, PhTeI3 or PhTeI2HC = CPhI results in different PhTeI-containing complexes of Fe, Mn or Co. The molecular structures of all new compounds were studied by means of X-ray diffraction analyses and the mechanism of M-Te bond shortening is discussed.

AB - The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes of organometallic compounds: (1) formally electron-deficient species with additional donor-acceptor interaction between Te lone pairs and half-occupied d-orbitals of M; (2) formally electron-saturated species having additional dative interaction between M lone pairs and LUMO of Te. These compounds could be prepared by two main methods: (a) interaction of [CpMn(CO)2PhC(O)-]Li+ with Te proceeds via formation of intermediate {[CpMn(CO)2]2Te}2- which is further transformed into binuclear complex [CpMn(CO)2] 2Te(CH2Ph)2 or into trinuclear ditelluride cluster [CpMn(CO)2]3Te2 on one hand or to mixed-metal monotelluride clusters [CpMn(CO)2]2TeM(CO) 5 on another hand. (b) treatment of Fe(CO)5, CpMn(CO) 2(THF) or Me4C4Co(CO)2I with [PhTeI]4, PhTeI3 or PhTeI2HC = CPhI results in different PhTeI-containing complexes of Fe, Mn or Co. The molecular structures of all new compounds were studied by means of X-ray diffraction analyses and the mechanism of M-Te bond shortening is discussed.

KW - Chromium

KW - Cobalt

KW - Cyclopentadienyl complexes

KW - Iron

KW - Manganese

KW - Metal carbonyls

KW - Metal tellurides

KW - Mixed-metal clusters

KW - Tungsten

KW - X-ray analyses

UR - https://www.scopus.com/pages/publications/67349162995

U2 - 10.1007/s10876-008-0227-0

DO - 10.1007/s10876-008-0227-0

M3 - Article

AN - SCOPUS:67349162995

SN - 1040-7278

VL - 20

SP - 193

EP - 204

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

The shortened transition metal-tellurium bonds in organometallic clusters

Abstract

Keywords

ASJC Scopus subject areas

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