The synergy between electrochemical substrate oxidation and the oxygen reduction reaction to enable aerobic oxidation

Snehanjali Behera; SK Tarik Aziz; Nisha Singla; Biswajit Mondal

doi:10.1039/d3cc02428h

The synergy between electrochemical substrate oxidation and the oxygen reduction reaction to enable aerobic oxidation

Snehanjali Behera, SK Tarik Aziz, Nisha Singla, Biswajit Mondal

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Aerobic substrate oxidation reactions catalyzed by a heterogeneous catalyst can be looked upon as two independent half-cell reactions, viz. anodic substrate oxidation and the cathodic oxygen reduction reaction (ORR). In this context, Fe PANI/C, a well-known catalyst for the ORR, is chosen to validate this hypothesis, wherein the anodic reaction is hydrazine oxidation. Fe PANI/C shows excellent activity in terms of the electrochemical ORR and hydrazine oxidation in both alkaline aqueous and non-aqueous media and taken together the aerobic oxidation efficacy of hydrazine-like small organic molecules is correlated with the electrochemical outcomes.

Original language	English
Pages (from-to)	11528-11531
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	77
DOIs	https://doi.org/10.1039/d3cc02428h
State	Published - 31 Aug 2023
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc02428h

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title = "The synergy between electrochemical substrate oxidation and the oxygen reduction reaction to enable aerobic oxidation",

abstract = "Aerobic substrate oxidation reactions catalyzed by a heterogeneous catalyst can be looked upon as two independent half-cell reactions, viz. anodic substrate oxidation and the cathodic oxygen reduction reaction (ORR). In this context, Fe PANI/C, a well-known catalyst for the ORR, is chosen to validate this hypothesis, wherein the anodic reaction is hydrazine oxidation. Fe PANI/C shows excellent activity in terms of the electrochemical ORR and hydrazine oxidation in both alkaline aqueous and non-aqueous media and taken together the aerobic oxidation efficacy of hydrazine-like small organic molecules is correlated with the electrochemical outcomes.",

author = "Snehanjali Behera and Aziz, \{SK Tarik\} and Nisha Singla and Biswajit Mondal",

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year = "2023",

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T1 - The synergy between electrochemical substrate oxidation and the oxygen reduction reaction to enable aerobic oxidation

AU - Behera, Snehanjali

AU - Aziz, SK Tarik

AU - Singla, Nisha

AU - Mondal, Biswajit

PY - 2023/8/31

Y1 - 2023/8/31

N2 - Aerobic substrate oxidation reactions catalyzed by a heterogeneous catalyst can be looked upon as two independent half-cell reactions, viz. anodic substrate oxidation and the cathodic oxygen reduction reaction (ORR). In this context, Fe PANI/C, a well-known catalyst for the ORR, is chosen to validate this hypothesis, wherein the anodic reaction is hydrazine oxidation. Fe PANI/C shows excellent activity in terms of the electrochemical ORR and hydrazine oxidation in both alkaline aqueous and non-aqueous media and taken together the aerobic oxidation efficacy of hydrazine-like small organic molecules is correlated with the electrochemical outcomes.

AB - Aerobic substrate oxidation reactions catalyzed by a heterogeneous catalyst can be looked upon as two independent half-cell reactions, viz. anodic substrate oxidation and the cathodic oxygen reduction reaction (ORR). In this context, Fe PANI/C, a well-known catalyst for the ORR, is chosen to validate this hypothesis, wherein the anodic reaction is hydrazine oxidation. Fe PANI/C shows excellent activity in terms of the electrochemical ORR and hydrazine oxidation in both alkaline aqueous and non-aqueous media and taken together the aerobic oxidation efficacy of hydrazine-like small organic molecules is correlated with the electrochemical outcomes.

UR - https://www.scopus.com/pages/publications/85171479214

U2 - 10.1039/d3cc02428h

DO - 10.1039/d3cc02428h

M3 - Article

C2 - 37672289

AN - SCOPUS:85171479214

SN - 1359-7345

VL - 59

SP - 11528

EP - 11531

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

The synergy between electrochemical substrate oxidation and the oxygen reduction reaction to enable aerobic oxidation

Abstract

ASJC Scopus subject areas

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