The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides: Diamagnetic Mn2(CO)8(μ-TePh)2 and paramagnetic Mn2(CO)6(μ-TePh)3

A. A. Pasynskii; Yu V. Torubaev; I. L. Eremenko; D. A. Vegini; A. I. Yanovskii; Yu T. Struchkov

The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides: Diamagnetic Mn₂(CO)₈(μ-TePh)₂ and paramagnetic Mn₂(CO)₆(μ-TePh)₃

A. A. Pasynskii, Yu V. Torubaev, I. L. Eremenko, D. A. Vegini, A. I. Yanovskii, Yu T. Struchkov

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Heating MnBr(CO)₅ with Ph₂Te₂ in boiling benzene yields diamagnetic Mn₂(CO)₈(μ-TePh)₂ (I), while the photochemical reaction of Mn₂(CO)₁₀ with Ph₂Te₂ in boiling tetrahydrofuran yields paramagnetic Mn₂(CO)₆(μ-TePh)₃ (II) containing one unpaired electron (μ_eff = 2.5 μ_B at 296-78 K). According to X-ray structural analysis, I and II contain two and three PhTe bridges respectively. The Mn-Te bonds in II [2.622(1)-2.654(1) Å] are slightly shortened compared to those in I [2.655(6)-2.684(7) Å]. No Mn-Mn bonding occurs in I [Mn⋯Mn distances are 3.921(6) and 4.019(6) Å in the two independent molecules; MnTeMn angles are 95.2(2) and 97.2(2)° respectively], while one-electron metal-metal bonding is observed in II [Mn-Mn 3.058(1) Å MnTeMn angle 70.5(1)-71.2(1)°].

Original language	English
Pages (from-to)	866-869
Number of pages	4
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	22
Issue number	12
State	Published - 1 Dec 1996

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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@article{f799f978f7f6487b9ff9fe0a054729d5,

title = "The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides: Diamagnetic Mn2(CO)8(μ-TePh)2 and paramagnetic Mn2(CO)6(μ-TePh)3",

abstract = "Heating MnBr(CO)5 with Ph2Te2 in boiling benzene yields diamagnetic Mn2(CO)8(μ-TePh)2 (I), while the photochemical reaction of Mn2(CO)10 with Ph2Te2 in boiling tetrahydrofuran yields paramagnetic Mn2(CO)6(μ-TePh)3 (II) containing one unpaired electron (μeff = 2.5 μB at 296-78 K). According to X-ray structural analysis, I and II contain two and three PhTe bridges respectively. The Mn-Te bonds in II [2.622(1)-2.654(1) {\AA}] are slightly shortened compared to those in I [2.655(6)-2.684(7) {\AA}]. No Mn-Mn bonding occurs in I [Mn⋯Mn distances are 3.921(6) and 4.019(6) {\AA} in the two independent molecules; MnTeMn angles are 95.2(2) and 97.2(2)° respectively], while one-electron metal-metal bonding is observed in II [Mn-Mn 3.058(1) {\AA} MnTeMn angle 70.5(1)-71.2(1)°].",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Eremenko, {I. L.} and Vegini, {D. A.} and Yanovskii, {A. I.} and Struchkov, {Yu T.}",

year = "1996",

month = dec,

day = "1",

language = "English",

volume = "22",

pages = "866--869",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "12",

}

The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides: Diamagnetic Mn₂(CO)₈(μ-TePh)₂ and paramagnetic Mn₂(CO)₆(μ-TePh)₃. / Pasynskii, A. A.; Torubaev, Yu V.; Eremenko, I. L. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 22, No. 12, 01.12.1996, p. 866-869.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides

T2 - Diamagnetic Mn2(CO)8(μ-TePh)2 and paramagnetic Mn2(CO)6(μ-TePh)3

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Eremenko, I. L.

AU - Vegini, D. A.

AU - Yanovskii, A. I.

AU - Struchkov, Yu T.

PY - 1996/12/1

Y1 - 1996/12/1

N2 - Heating MnBr(CO)5 with Ph2Te2 in boiling benzene yields diamagnetic Mn2(CO)8(μ-TePh)2 (I), while the photochemical reaction of Mn2(CO)10 with Ph2Te2 in boiling tetrahydrofuran yields paramagnetic Mn2(CO)6(μ-TePh)3 (II) containing one unpaired electron (μeff = 2.5 μB at 296-78 K). According to X-ray structural analysis, I and II contain two and three PhTe bridges respectively. The Mn-Te bonds in II [2.622(1)-2.654(1) Å] are slightly shortened compared to those in I [2.655(6)-2.684(7) Å]. No Mn-Mn bonding occurs in I [Mn⋯Mn distances are 3.921(6) and 4.019(6) Å in the two independent molecules; MnTeMn angles are 95.2(2) and 97.2(2)° respectively], while one-electron metal-metal bonding is observed in II [Mn-Mn 3.058(1) Å MnTeMn angle 70.5(1)-71.2(1)°].

AB - Heating MnBr(CO)5 with Ph2Te2 in boiling benzene yields diamagnetic Mn2(CO)8(μ-TePh)2 (I), while the photochemical reaction of Mn2(CO)10 with Ph2Te2 in boiling tetrahydrofuran yields paramagnetic Mn2(CO)6(μ-TePh)3 (II) containing one unpaired electron (μeff = 2.5 μB at 296-78 K). According to X-ray structural analysis, I and II contain two and three PhTe bridges respectively. The Mn-Te bonds in II [2.622(1)-2.654(1) Å] are slightly shortened compared to those in I [2.655(6)-2.684(7) Å]. No Mn-Mn bonding occurs in I [Mn⋯Mn distances are 3.921(6) and 4.019(6) Å in the two independent molecules; MnTeMn angles are 95.2(2) and 97.2(2)° respectively], while one-electron metal-metal bonding is observed in II [Mn-Mn 3.058(1) Å MnTeMn angle 70.5(1)-71.2(1)°].

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M3 - Article

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SN - 1070-3284

VL - 22

SP - 866

EP - 869

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 12

ER -

The syntheses and molecular structures of binuclear manganese carbonyl phenyltellurides: Diamagnetic Mn₂(CO)₈(μ-TePh)₂ and paramagnetic Mn₂(CO)₆(μ-TePh)₃

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