The synthesis and characterization of the meso-meso linked antiaromatic tetraoxa isophlorin dimer

Baddigam Kiran Reddy; Santosh C. Gadekar; Venkataramanarao G. Anand

doi:10.1039/c5cc10370c

The synthesis and characterization of the meso-meso linked antiaromatic tetraoxa isophlorin dimer

Baddigam Kiran Reddy, Santosh C. Gadekar, Venkataramanarao G. Anand

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The first synthesis of meso-meso linked antiaromatic isophlorin has been described. The synthetic pathway is different from the routinely employed oxidative coupling of meso free porphyrin into its dimer and oligomers. Spectroscopic and structural analyses revealed paratropic ring current effects and each unit was found to be orthogonal to each other.

Original language	English
Pages (from-to)	3007-3009
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	14
DOIs	https://doi.org/10.1039/c5cc10370c
State	Published - 1 Jan 2016
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc10370c

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abstract = "The first synthesis of meso-meso linked antiaromatic isophlorin has been described. The synthetic pathway is different from the routinely employed oxidative coupling of meso free porphyrin into its dimer and oligomers. Spectroscopic and structural analyses revealed paratropic ring current effects and each unit was found to be orthogonal to each other.",

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AU - Anand, Venkataramanarao G.

PY - 2016/1/1

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AB - The first synthesis of meso-meso linked antiaromatic isophlorin has been described. The synthetic pathway is different from the routinely employed oxidative coupling of meso free porphyrin into its dimer and oligomers. Spectroscopic and structural analyses revealed paratropic ring current effects and each unit was found to be orthogonal to each other.

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The synthesis and characterization of the meso-meso linked antiaromatic tetraoxa isophlorin dimer

Abstract

ASJC Scopus subject areas

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