The Thermal Decomposition of Ammonium Perchlorate Doped with Cu+2 and Mn+2

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Abstract

The thermal decomposition of ammonium perchlorate doped with Cu+2 and Mn+2 was studied, using DTA and TGA. Small concentrations (0.1 − 0.01%) of these ions inhibit the decomposition by eliminating the first exotherm. At higher concentrations a catalyzed decomposition is observed. Either the influence of doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.

Original languageEnglish
Pages (from-to)171-180
Number of pages10
JournalIsrael Journal of Chemistry
Volume13
Issue number3
DOIs
StatePublished - 1 Jan 1975

ASJC Scopus subject areas

  • Chemistry (all)

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