The thermal decomposition of doped ammonium perchlorate

I. Pelly

doi:10.1016/0040-6031(82)87004-4

The thermal decomposition of doped ammonium perchlorate

I. Pelly

Department of Earth and Environmental sciences

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The thermal decomposition of ammonium perchlorate doped with Cu²⁺, Mn²⁺, Co²⁺ and Fe³⁺ (with and without H⁺) was studied using DTA and TG. Small concentrations of these ions inhibit the decomposition by eliminating the first exothermic peak. At higher concentrations, a catalyzed decomposition is observed. Either the influence of the doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.

Original language	English
Pages (from-to)	27-34
Number of pages	8
Journal	Thermochimica Acta
Volume	55
Issue number	1
DOIs	https://doi.org/10.1016/0040-6031(82)87004-4
State	Published - 1 May 1982

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1016/0040-6031(82)87004-4

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title = "The thermal decomposition of doped ammonium perchlorate",

abstract = "The thermal decomposition of ammonium perchlorate doped with Cu2+, Mn2+, Co2+ and Fe3+ (with and without H+) was studied using DTA and TG. Small concentrations of these ions inhibit the decomposition by eliminating the first exothermic peak. At higher concentrations, a catalyzed decomposition is observed. Either the influence of the doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.",

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N2 - The thermal decomposition of ammonium perchlorate doped with Cu2+, Mn2+, Co2+ and Fe3+ (with and without H+) was studied using DTA and TG. Small concentrations of these ions inhibit the decomposition by eliminating the first exothermic peak. At higher concentrations, a catalyzed decomposition is observed. Either the influence of the doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.

AB - The thermal decomposition of ammonium perchlorate doped with Cu2+, Mn2+, Co2+ and Fe3+ (with and without H+) was studied using DTA and TG. Small concentrations of these ions inhibit the decomposition by eliminating the first exothermic peak. At higher concentrations, a catalyzed decomposition is observed. Either the influence of the doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.

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M3 - Article

AN - SCOPUS:33644966803

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JO - Thermochimica Acta

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ER -

The thermal decomposition of doped ammonium perchlorate

Abstract

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