The unsymmetrical silaketal as a neutral, removable tether for effecting intramolecular diels-alder reactions.

John W. Gillard; Réjean Fortin; Erich L. Grimm; Michel Maillard; Michael Tjepkema; Michael A. Bernstein; Robert Glaser

doi:10.1016/S0040-4039(00)92029-X

The unsymmetrical silaketal as a neutral, removable tether for effecting intramolecular diels-alder reactions.

John W. Gillard, Réjean Fortin, Erich L. Grimm, Michel Maillard, Michael Tjepkema, Michael A. Bernstein, Robert Glaser

Research output: Contribution to journal › Article › peer-review

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Abstract

Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with a high degree of stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.

Original language	English
Pages (from-to)	1145-1148
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)92029-X
State	Published - 25 Feb 1991
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)92029-X

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title = "The unsymmetrical silaketal as a neutral, removable tether for effecting intramolecular diels-alder reactions.",

abstract = "Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with a high degree of stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.",

author = "Gillard, {John W.} and R{\'e}jean Fortin and Grimm, {Erich L.} and Michel Maillard and Michael Tjepkema and Bernstein, {Michael A.} and Robert Glaser",

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AU - Gillard, John W.

AU - Fortin, Réjean

AU - Grimm, Erich L.

AU - Maillard, Michel

AU - Tjepkema, Michael

AU - Bernstein, Michael A.

AU - Glaser, Robert

PY - 1991/2/25

Y1 - 1991/2/25

N2 - Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with a high degree of stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.

AB - Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with a high degree of stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.

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U2 - 10.1016/S0040-4039(00)92029-X

DO - 10.1016/S0040-4039(00)92029-X

M3 - Article

AN - SCOPUS:0026011854

SN - 0040-4039

VL - 32

SP - 1145

EP - 1148

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 9

ER -

The unsymmetrical silaketal as a neutral, removable tether for effecting intramolecular diels-alder reactions.

Abstract

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