Thermal analysis of the polymerization process on the surface of inorganic fillers

E. Gutman; A. Bobovitch; A. Pinski; L. Utevski; D. Sondak; M. Muskatel

doi:10.1007/BF01980760

Thermal analysis of the polymerization process on the surface of inorganic fillers

E. Gutman, A. Bobovitch, A. Pinski, L. Utevski, D. Sondak, M. Muskatel

Department of Materials Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The thermal polymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of the inorganic fillers Mg(OH)₂ and CaCO₃ was studied. FTIR spectroscopy and extraction of the polymer in bromobenzene show that polypentabromobenzyl acrylate (PBB-PA) was mostly grafted on the surface of Mg(OH)₂. Thermal analysis (TG, DSC, isothermal DSC (IDSC)) demonstrated an increase in polymerization starting temperature, and differences in polymerization enthalpy and apparent activation energy when an inorganic filler is added. These differences depend on the chemical composition of the filler used.

Original language	English
Pages (from-to)	1541-1550
Number of pages	10
Journal	Journal of Thermal Analysis
Volume	46
Issue number	6
DOIs	https://doi.org/10.1007/BF01980760
State	Published - 1 Jan 1996

Keywords

DSC
FTIR
Grafting
IDSC
Kinetic parameters
Polymerization
TG
Thermodynamic parameters

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Engineering

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10.1007/BF01980760

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title = "Thermal analysis of the polymerization process on the surface of inorganic fillers",

abstract = "The thermal polymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of the inorganic fillers Mg(OH)2 and CaCO3 was studied. FTIR spectroscopy and extraction of the polymer in bromobenzene show that polypentabromobenzyl acrylate (PBB-PA) was mostly grafted on the surface of Mg(OH)2. Thermal analysis (TG, DSC, isothermal DSC (IDSC)) demonstrated an increase in polymerization starting temperature, and differences in polymerization enthalpy and apparent activation energy when an inorganic filler is added. These differences depend on the chemical composition of the filler used.",

keywords = "DSC, FTIR, Grafting, IDSC, Kinetic parameters, Polymerization, TG, Thermodynamic parameters",

author = "E. Gutman and A. Bobovitch and A. Pinski and L. Utevski and D. Sondak and M. Muskatel",

year = "1996",

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T1 - Thermal analysis of the polymerization process on the surface of inorganic fillers

AU - Gutman, E.

AU - Bobovitch, A.

AU - Pinski, A.

AU - Utevski, L.

AU - Sondak, D.

AU - Muskatel, M.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The thermal polymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of the inorganic fillers Mg(OH)2 and CaCO3 was studied. FTIR spectroscopy and extraction of the polymer in bromobenzene show that polypentabromobenzyl acrylate (PBB-PA) was mostly grafted on the surface of Mg(OH)2. Thermal analysis (TG, DSC, isothermal DSC (IDSC)) demonstrated an increase in polymerization starting temperature, and differences in polymerization enthalpy and apparent activation energy when an inorganic filler is added. These differences depend on the chemical composition of the filler used.

AB - The thermal polymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of the inorganic fillers Mg(OH)2 and CaCO3 was studied. FTIR spectroscopy and extraction of the polymer in bromobenzene show that polypentabromobenzyl acrylate (PBB-PA) was mostly grafted on the surface of Mg(OH)2. Thermal analysis (TG, DSC, isothermal DSC (IDSC)) demonstrated an increase in polymerization starting temperature, and differences in polymerization enthalpy and apparent activation energy when an inorganic filler is added. These differences depend on the chemical composition of the filler used.

KW - DSC

KW - FTIR

KW - Grafting

KW - IDSC

KW - Kinetic parameters

KW - Polymerization

KW - TG

KW - Thermodynamic parameters

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U2 - 10.1007/BF01980760

DO - 10.1007/BF01980760

M3 - Article

AN - SCOPUS:0030174386

SN - 0368-4466

VL - 46

SP - 1541

EP - 1550

JO - Journal of Thermal Analysis

JF - Journal of Thermal Analysis

IS - 6

ER -

Thermal analysis of the polymerization process on the surface of inorganic fillers

Abstract

Keywords

ASJC Scopus subject areas

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