Thermal decomposition of nitrosyl and nitryl perchlorate-II. Reactions with metal oxides

A. Glasner; I. Pelly; M. Steinberg

doi:10.1016/0022-1902(70)80446-8

Thermal decomposition of nitrosyl and nitryl perchlorate-II. Reactions with metal oxides

A. Glasner, I. Pelly, M. Steinberg

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Abstract

The decomposition of mixtures of metal oxides with NOClO₄ or NO₂ClO₄ was studied by gasometry, thermogravimetry, D.T.A. and i.r. absorption. It is shown that NOClO₄ is first converted to NO₂ClO₄, which reacts with some of the oxides to form the corresponding metal perchlorate. The weight loss indicated by the thermogravimetric curves is in quantitative accord with this description and the mechanism previously proposed for the decomposition of NOClO₄.

Original language	English
Pages (from-to)	33-41
Number of pages	9
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/0022-1902(70)80446-8
State	Published - 1 Jan 1970
Externally published	Yes

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title = "Thermal decomposition of nitrosyl and nitryl perchlorate-II. Reactions with metal oxides",

abstract = "The decomposition of mixtures of metal oxides with NOClO4 or NO2ClO4 was studied by gasometry, thermogravimetry, D.T.A. and i.r. absorption. It is shown that NOClO4 is first converted to NO2ClO4, which reacts with some of the oxides to form the corresponding metal perchlorate. The weight loss indicated by the thermogravimetric curves is in quantitative accord with this description and the mechanism previously proposed for the decomposition of NOClO4.",

author = "A. Glasner and I. Pelly and M. Steinberg",

year = "1970",

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doi = "10.1016/0022-1902(70)80446-8",

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T1 - Thermal decomposition of nitrosyl and nitryl perchlorate-II. Reactions with metal oxides

AU - Glasner, A.

AU - Pelly, I.

AU - Steinberg, M.

PY - 1970/1/1

Y1 - 1970/1/1

N2 - The decomposition of mixtures of metal oxides with NOClO4 or NO2ClO4 was studied by gasometry, thermogravimetry, D.T.A. and i.r. absorption. It is shown that NOClO4 is first converted to NO2ClO4, which reacts with some of the oxides to form the corresponding metal perchlorate. The weight loss indicated by the thermogravimetric curves is in quantitative accord with this description and the mechanism previously proposed for the decomposition of NOClO4.

AB - The decomposition of mixtures of metal oxides with NOClO4 or NO2ClO4 was studied by gasometry, thermogravimetry, D.T.A. and i.r. absorption. It is shown that NOClO4 is first converted to NO2ClO4, which reacts with some of the oxides to form the corresponding metal perchlorate. The weight loss indicated by the thermogravimetric curves is in quantitative accord with this description and the mechanism previously proposed for the decomposition of NOClO4.

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U2 - 10.1016/0022-1902(70)80446-8

DO - 10.1016/0022-1902(70)80446-8

M3 - Article

AN - SCOPUS:49849116207

SN - 0022-1902

VL - 32

SP - 33

EP - 41

JO - Journal of Inorganic and Nuclear Chemistry

JF - Journal of Inorganic and Nuclear Chemistry

IS - 1

ER -

Thermal decomposition of nitrosyl and nitryl perchlorate-II. Reactions with metal oxides

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