Thermal decomposition of nitrosyl perchlorate and nitryl perchlorate-I. Mechanism of decomposition

A. Glasner; I. Pelly; M. Steinberg

doi:10.1016/0022-1902(69)80322-2

Thermal decomposition of nitrosyl perchlorate and nitryl perchlorate-I. Mechanism of decomposition

A. Glasner, I. Pelly, M. Steinberg

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Abstract

The thermal decomposition of NOClO₄ (powder, or fragments of pressed pellets) and of NO₂ClO₄ (granules) has been studied gasometrically and by X-ray diffraction. During the decomposition of NOClO₄, NO₂ClO₄ is formed as an intermediate. The following mechanism is suggested for the decomposition of NOClO₄: NOCl₄→ClO₃+NO₂, 3NOClO₄+ClO3→ 1 2+3NO₂ClO₄, 3NO₂ClO₄→3ClO₂+3NO₂+3o₂. NO₂ClO₄ is partly reduced to NOClO₄. Independently of the initial sample, the reaction mixture will contain both perchlorates.

Original language	English
Pages (from-to)	3395-3404
Number of pages	10
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	31
Issue number	11
DOIs	https://doi.org/10.1016/0022-1902(69)80322-2
State	Published - 1 Jan 1969
Externally published	Yes

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title = "Thermal decomposition of nitrosyl perchlorate and nitryl perchlorate-I. Mechanism of decomposition",

abstract = "The thermal decomposition of NOClO4 (powder, or fragments of pressed pellets) and of NO2ClO4 (granules) has been studied gasometrically and by X-ray diffraction. During the decomposition of NOClO4, NO2ClO4 is formed as an intermediate. The following mechanism is suggested for the decomposition of NOClO4: NOCl4→ClO3+NO2, 3NOClO4+ClO3→ 1 2+3NO2ClO4, 3NO2ClO4→3ClO2+3NO2+3o2. NO2ClO4 is partly reduced to NOClO4. Independently of the initial sample, the reaction mixture will contain both perchlorates.",

author = "A. Glasner and I. Pelly and M. Steinberg",

year = "1969",

month = jan,

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doi = "10.1016/0022-1902(69)80322-2",

language = "English",

volume = "31",

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journal = "Journal of Inorganic and Nuclear Chemistry",

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TY - JOUR

T1 - Thermal decomposition of nitrosyl perchlorate and nitryl perchlorate-I. Mechanism of decomposition

AU - Glasner, A.

AU - Pelly, I.

AU - Steinberg, M.

PY - 1969/1/1

Y1 - 1969/1/1

N2 - The thermal decomposition of NOClO4 (powder, or fragments of pressed pellets) and of NO2ClO4 (granules) has been studied gasometrically and by X-ray diffraction. During the decomposition of NOClO4, NO2ClO4 is formed as an intermediate. The following mechanism is suggested for the decomposition of NOClO4: NOCl4→ClO3+NO2, 3NOClO4+ClO3→ 1 2+3NO2ClO4, 3NO2ClO4→3ClO2+3NO2+3o2. NO2ClO4 is partly reduced to NOClO4. Independently of the initial sample, the reaction mixture will contain both perchlorates.

AB - The thermal decomposition of NOClO4 (powder, or fragments of pressed pellets) and of NO2ClO4 (granules) has been studied gasometrically and by X-ray diffraction. During the decomposition of NOClO4, NO2ClO4 is formed as an intermediate. The following mechanism is suggested for the decomposition of NOClO4: NOCl4→ClO3+NO2, 3NOClO4+ClO3→ 1 2+3NO2ClO4, 3NO2ClO4→3ClO2+3NO2+3o2. NO2ClO4 is partly reduced to NOClO4. Independently of the initial sample, the reaction mixture will contain both perchlorates.

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U2 - 10.1016/0022-1902(69)80322-2

DO - 10.1016/0022-1902(69)80322-2

M3 - Article

AN - SCOPUS:33751265214

SN - 0022-1902

VL - 31

SP - 3395

EP - 3404

JO - Journal of Inorganic and Nuclear Chemistry

JF - Journal of Inorganic and Nuclear Chemistry

IS - 11

ER -

Thermal decomposition of nitrosyl perchlorate and nitryl perchlorate-I. Mechanism of decomposition

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