Abstract
Sound velocities in aqueous 0.1, 0.5 and 1.0 mol·kg-1 lithium chloride solutions were determined at 1 K temperature intervals from 278.15 to 323.15 K. These velocities served to evaluate the isentropic compressibilities κ S , the isothermal compressibilities κ T , the apparent molar compressibilities K 2,φ , the isochoric thermal pressure coefficients (∂ P/∂ T) V , the change of cubic expansion coefficients with pressure at constant temperature (∂ α/∂ P) T , and the changes of heat capacities C V with volume (∂ C V /∂ V) T and C P with pressure (∂ C P /∂ P) T .
| Original language | English |
|---|---|
| Pages (from-to) | 1437-1456 |
| Number of pages | 20 |
| Journal | Journal of Solution Chemistry |
| Volume | 36 |
| Issue number | 11-12 |
| DOIs | |
| State | Published - 1 Dec 2007 |
Keywords
- Aqueous lithium chloride solutions
- Cubic expansion coefficient changes with pressure
- Heat capacities changes with volume and pressure
- Isochoric thermal pressure coefficients
- Isothermal and adiabatic compressibilities
- Sound velocities
ASJC Scopus subject areas
- Biophysics
- Biochemistry
- Molecular Biology
- Physical and Theoretical Chemistry
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