Thermodynamic properties of associated solutions. I. Mixtures of the type A + B + AB2

Alexander Apelblat

doi:10.1021/j100909a031

Thermodynamic properties of associated solutions. I. Mixtures of the type A + B + AB₂

Alexander Apelblat

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17 Scopus citations

Abstract

The theory of ideal associated solutions of the type A + B + AB₂ has been investigated in detail. The chemical equilibrium, the activity coefficients, the excess thermodynamic functions, and the standard reaction parameters were considered. Special attention was directed towards the evaluation of the boiling and condensation temperature curves for these solutions and the conditions necessary for the occurrence of an azeotrope. The theoretical predictions for the A + B + AB₂ model were compared with experimental data for binary methanolpropionic acid systems.

Original language	English
Pages (from-to)	2214-2220
Number of pages	7
Journal	Journal of Physical Chemistry
Volume	74
Issue number	10
DOIs	https://doi.org/10.1021/j100909a031
State	Published - 1 Jan 1970
Externally published	Yes

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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10.1021/j100909a031

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AB - The theory of ideal associated solutions of the type A + B + AB2 has been investigated in detail. The chemical equilibrium, the activity coefficients, the excess thermodynamic functions, and the standard reaction parameters were considered. Special attention was directed towards the evaluation of the boiling and condensation temperature curves for these solutions and the conditions necessary for the occurrence of an azeotrope. The theoretical predictions for the A + B + AB2 model were compared with experimental data for binary methanolpropionic acid systems.

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Thermodynamic properties of associated solutions. I. Mixtures of the type A + B + AB₂

Abstract

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