Thermodynamic studies of solvent extraction systems-III. The binary mixtures of methyl diphenyl phosphate with hexane and water

Alexander Apelblat

doi:10.1016/0022-1902(78)80225-5

Thermodynamic studies of solvent extraction systems-III. The binary mixtures of methyl diphenyl phosphate with hexane and water

Alexander Apelblat

Department of Chemical Engineering

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Abstract

Total vapour pressures were measured between 25-45°C in the methyl diphenyl phosphate-hexane system and between 25-75°C in the methyl diphenyl phosphate-water system. From the obtained data, the activity coefficients and the excess free energies of mixing were calculated. Both systems show strong positive deviations from ideal behaviour, which are sufficient to produce phase separation.

Original language	English
Pages (from-to)	1783-1785
Number of pages	3
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	40
Issue number	10
DOIs	https://doi.org/10.1016/0022-1902(78)80225-5
State	Published - 1 Jan 1978

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title = "Thermodynamic studies of solvent extraction systems-III. The binary mixtures of methyl diphenyl phosphate with hexane and water",

abstract = "Total vapour pressures were measured between 25-45°C in the methyl diphenyl phosphate-hexane system and between 25-75°C in the methyl diphenyl phosphate-water system. From the obtained data, the activity coefficients and the excess free energies of mixing were calculated. Both systems show strong positive deviations from ideal behaviour, which are sufficient to produce phase separation.",

author = "Alexander Apelblat",

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AB - Total vapour pressures were measured between 25-45°C in the methyl diphenyl phosphate-hexane system and between 25-75°C in the methyl diphenyl phosphate-water system. From the obtained data, the activity coefficients and the excess free energies of mixing were calculated. Both systems show strong positive deviations from ideal behaviour, which are sufficient to produce phase separation.

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Thermodynamic studies of solvent extraction systems-III. The binary mixtures of methyl diphenyl phosphate with hexane and water

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